Chemical Forums
Chemistry Forums for Students => Undergraduate General Chemistry Forum => Topic started by: GreenAssailant on November 27, 2011, 08:59:10 AM
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4.0g of ferrous ammonium sulphate, FeSO4 ∙ (NH4)2SO4 ∙ 6H2O is used. Since the oxalate is in excess, calculate the theoretical yield of the iron complex.
NOTE: We assume 100% conversion efficiency, going from 1 reaction to the next.
3 separate equations in a reaction series:
[1] FeSO4∙(NH4)2SO4∙ 6H2O + H2C2O4∙ 2H2O ---> FeC2O4 + (NH4)2SO4 + H2SO4 + 8H2O
[2] 6 FeC2O4 + 3H2O2 + 6K2C2O4∙ H2O ---> 4 K3[Fe(C2O4)3]∙ 3 H2O + 2 Fe(OH)3 + 6 H2O
[3] 2 Fe(OH)3 + 3 H2C2O4∙ 2H2O + 3 K2C2O4∙ H2O ----> 2 K3[Fe(C2O4)3]∙ 3H2O + 9 H2O
Attempt:
I found the molar mass of ammonium sulphate hydrate compound to be:
m[FeSO4∙(NH4)2 SO4∙6H2O] = 392.21 g/mol
Because we assume that the oxalate is in excess, that means the ammonium sulphate hydrate compound is obviously the limiting reagent. So I use molar mass and the grams provided to get the moles, which is:
mol[FeSO4∙(NH4)2 SO4∙6H2O] = 0.010198618 mol
Now, I get the moles of each product of the r'xn using the mol[FeSO4∙(NH4)2 SO4∙6H2O], but I am experiencing dilemma:
mol[FeC2O4] = mol[(NH4)2SO4] = mol[H2SO4]
^ All of these products have the same amount of moles produced.
My question is: which one do I use to proceed to the next reaction?
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The moles are correct. But write 0.01 mol is enough.
Now check how many mole ammonia iron sulfate correspond to the Oxalate complex. The equations between are not important. Write on the right side your product.