Chemical Forums

Chemistry Forums for Students => Undergraduate General Chemistry Forum => Topic started by: mrmiyagi on April 24, 2012, 10:15:04 PM

Title: need help with electrochemistry and liquid junctions
Post by: mrmiyagi on April 24, 2012, 10:15:04 PM
the question pertains to this:
Pt(s)/H2(g)/HBr(aq)/AgBr(s)/Ag(s)

It asks why a liquid junction is not necessary. So I know AgBr is insoluble in water, and AgBr coats the silver metal. I just don't understand why it does not matter that the Br- anions from AgBr mixing with the H+ cations doesn't necessitate a liquid junction. Any help?