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Chemistry Forums for Students => Undergraduate General Chemistry Forum => Topic started by: luketapis on December 06, 2012, 05:17:37 AM

Title: Colors of TM complexes
Post by: luketapis on December 06, 2012, 05:17:37 AM
Hi I have a question:
The two complexes [NI(OH2)2]2+ and [Ni(NH3)]2+
are both colored. One is green, the other is blue. Which is which?

Ok, so both complexes are octahedral and d8
[NI(OH2)2]2+ is high spin and weak field.
[Ni(NH3)]2+ is strong field ligand = low spin.
How from this information distinguish colors?
Title: Re: Colors of TM complexes
Post by: sjb on December 06, 2012, 05:25:58 AM
Hi I have a question:
The two complexes [NI(OH2)2]2+ and [Ni(NH3)]2+
are both colored. One is green, the other is blue. Which is which?

Ok, so both complexes are octahedral and d8
[NI(OH2)2]2+ is high spin and weak field.
[Ni(NH3)]2+ is strong field ligand = low spin.
How from this information distinguish colors?

What is the cause of the colour?
Title: Re: Colors of TM complexes
Post by: luketapis on December 06, 2012, 06:04:29 AM
absorption of light with a particular wavelength
Title: Re: Colors of TM complexes
Post by: sjb on December 06, 2012, 07:27:49 AM
absorption of light with a particular wavelength

And on a physical level, what is happening?
Title: Re: Colors of TM complexes
Post by: luketapis on December 06, 2012, 05:59:52 PM
d-d transition
Title: Re: Colors of TM complexes
Post by: sjb on December 09, 2012, 04:03:09 AM
Sorry, missed the reply. That sounds good (possibly d  :rarrow: d*, if I remember right, but it's been a while). So, if the energy gap between these levels is small, what does that mean for the light absorbed in the transition?
Title: Re: Colors of TM complexes
Post by: luketapis on December 09, 2012, 06:40:18 AM
I don't know
Title: Re: Colors of TM complexes
Post by: sjb on December 10, 2012, 05:18:56 PM
Do you know any relationship between frequency of light and energy?