Chemical Forums
Chemistry Forums for Students => Organic Chemistry Forum => Topic started by: theanonymous on January 14, 2013, 06:36:49 PM
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(http://i11.photobucket.com/albums/a179/slourg/Question1A_zpscaf7f3db.png)
Did I select the right answers?
I know that the Huckel numbers are 2, 6, 10, 14, 18, etc, pi electrons
And A only has 4 pi electrons (those 2 lines inside of it).
I need help with the other ones as well.
(http://i11.photobucket.com/albums/a179/slourg/B-E_zps3428df63.png)
(http://i11.photobucket.com/albums/a179/slourg/E-H_zps5ce44af8.png)
(http://i11.photobucket.com/albums/a179/slourg/I-J_zpsa14e8757.png)
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Are my answers correct?
A. 4 pi electrons antiaromatic
- does not contain a Huckel number of pi electrons
- there is at least one ring atom that does not contribute a pure p-orbital to the pi system
- the species is not aromatic
B. 4 pi electrons, antiaromatic
- does not contain a Huckel number of pi electrons
- there is at least one ring atom that does not contribute a pure p-orbital to the pi system
- the species is not aromatic
C. 6 pi electrons + 2 nonbonding electrons that are not part of the pi system
- contain a Huckel number of pi electrons
- there is at least one ring atom that does not contribute a pure p-orbital to the pi system
- the species is not aromatic
D. 6 pi electrons but nonplanar molecule
- contain a Huckel number of pi electrons
- there is at least one ring atom that does not contribute a pure p-orbital to the pi system
- the species is not aromatic
E. 6 pi electrons and planar = aromatic
- contains a Huckel number of pi electrons
- there is at least one ring atom that does not contribute a pure p-orbital to the pi system
- the species is aromatic
F. 8 pi electrons, antiaromatic
- the species is not aromatic
G. 14 pi electrons, aromatic
- contains a Huckel number of pi electrons
- each ring atom contributes a pure p-orbital to make a continuous pi system
- the species is aromatic
H. 6 pi electrons, aromatic with 1 pair on nonbonding electrons not part of the pi system
- contains a Huckel number of pi electrons
- there is at least one ring atom that does not contribute a pure p-orbital to the pi system
- the species is aromatic
I. 6 pi electrons (because of the +2 charge, so 8 pi electrons - 2 = 6, which is a Huckel number), aromatic
- contains a Huckel number of pi electrons
- each ring atom contributes a pure p-orbital to make a continuous pi system
- the species is aromatic
J. 8 pi electrons, antiaromatic
- does not contain a Huckel number of pi electrons
- each ring atom contributes a pure p-orbital to make a continuous pi system
- the species is not aromatic
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Hi,
A : NO the Boron atom has a (empty) pure p-orbital and this makes a continuous pi system.
B : OK
C : NO it is aromatic and there are only pure p-orbitals and they make a continuous pi system (S contributes to one pure pi and one pure sigma doublet, but the pure sigma does not matter in my opinion)
D : OK
E : NO as is A, there are only pure p-orbitals and they make a continuous pi system
F : NO you should add does not contain a Huckel number of pi electrons
G : ? this is complicated : as it is drawn, 2 cycles are aromatic but the right hand side on eis anti aromatic
H: NO there are only pure p-orbitals and they make a continuous pi system (as S in C, O has 1 pure-pi and 1 pure sigma doublet - and C has a pure (empty pure-pi orbital)
I : OK
J : OK
Amid
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Thanks so much!!!
I have one more quick question
I literally have 5 min to answer this. :(
(http://i11.photobucket.com/albums/a179/slourg/MOLECULES_zpsee6f1eb7.png)
A) Select all of the molecules that are aromatic
pyridine
pyrrole
imidazole
1,4-dioxine
furan
B) Select all of the molecules that contain a true lone pair.
pyridine
pyrrole
imidazole
1,4-dioxine
furan
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for part A I said pyridine and furan but they're both wrong :(