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Topic: Urgent! multipole expression and CN- intermolecular forces**  (Read 4525 times)

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Offline the_negro_puppy

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Urgent! multipole expression and CN- intermolecular forces**
« on: October 18, 2006, 07:15:20 PM »
Any help would be greatly appreciated

1) in the following multipole expression V(r,?) = -k z ?  (cos ? / r²)
What approximation was made?

2) The cyanide ion CN_ possesses a dipole moment. What types of intermolecular forces operate between the two cyanide ions, and which for will dominate their interactions.

So far i have:
Ion – Ion interactions
Ion-Dipole interactions
Short Range Repulsive Forces
Dispersion Forces (due to lone pairs on carbons)

and im not sure which force will dominate their interactions.

Offline Donaldson Tan

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Re: Urgent! multipole expression and CN- intermolecular forces**
« Reply #1 on: October 19, 2006, 05:47:35 PM »
Short Range Repulsive Forces
Dispersion Forces (due to lone pairs on carbons)

I assume gas phase, so there is no interaction with solvent molecules.

How close are the 2 cyanide ions?
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