UserInfo: February 09, 2010, 01:21:36 AM
Welcome, Guest. Please login or register.
Did you miss your activation email?

Login with username, password and session length
Forum Rules: Read This Before Posting  
   Home   Help Search Calendar Login Register  
Search Chemical Forums


Chemistry-Blog

 Geoengineering Science
  Chemistry-Blog.com




Google Sponsors

Content
Pages: [1]   Go Down
  Print  
Author Topic: superacid  (Read 1176 times)
0 Members and 1 Guest are viewing this topic.
abcc
Regular Member
***

Mole Snacks: +1/-5
Offline Offline

Posts: 86


View Profile
« on: December 01, 2006, 02:30:25 AM »

What are the applications of superacid  Huh
thx Wink
Logged

AWK
Global Moderator
Sr. Member
*****

Mole Snacks: +259/-77
Offline Offline

Gender: Male
Posts: 3525


View Profile
« Reply #1 on: December 01, 2006, 02:47:38 AM »

Google: superacid application
Logged

AWK

mdlhvn
Regular Member
***

Mole Snacks: +5/-2
Offline Offline

Posts: 63


View Profile
« Reply #2 on: December 01, 2006, 06:22:51 AM »

Thank you very much for your questioni. Actually, I have never heard superacid before. Now I think this link will help you a lot

http://en.wikipedia.org/wiki/Superacid
Logged
Alberto_Kravina
Assault Chemist
Staff
Full Member
*****

Mole Snacks: +67/-15
Offline Offline

Gender: Male
Posts: 596


Much too young chemist.


View Profile WWW
« Reply #3 on: December 01, 2006, 09:50:03 AM »

Check me on this, but I think that I've heard that superacids are used to create oxonium ions by protonating alcohols

Something like this: R-OH + H+ ? R-OH2+
Logged

Alberto
orpheus
New Member
**

Mole Snacks: +0/-0
Offline Offline

Posts: 5


View Profile
« Reply #4 on: December 12, 2006, 02:42:01 PM »

A reasonable working definition of  superacid, is an acid that is stronger than 100% H2SO4 (Sulphuric Acid). A classical example of a superacid is hydrofluoric acid, or HF. This is a very interesting inorganic acid to study and is one of the best organic and inorganic solvents available other than water.

HF can be used in heterogeneous catalysis, for example, you can functionalise a binary metal-oxide catalyst such as amorphous chromia or gamma-alumina (Al2O3) to produce a catalytically active substance. Evidence suggests that sub-surface insertion of the fluoride anion occurs and facilitates a through-lattice inductive effect that in turn alters the reactivity of Bronsted and Lewis acid sites on the surface of the catalyst.

The F-Al2O3 functionalised heterogeneous catalyst can then be used for a variety of industrial transformations, for example it can be used to produce the current drop-in replacement for CFC-12 (dichlorodifluromethane, that was banned under the Montreal protocol), that is,  1,1,1,2-tetrafluoroethane (HFC-134a) from 2-chloro-1,1,1-trifluoroethane (HCFC-133a) via a Cl for F halogen exchange mechanism.

This is an example of the use of a superacid (HF) in industrial heterogeneous catalysis.
Logged
Pages: [1]   Go Up
  Print  
 
Jump to:  

Powered by MySQL Powered by PHP
Mitch Andre Garcia's Chemical Forums 2003-Present.

Powered by SMF 1.1.11 | SMF © 2006-2008, Simple Machines LLC
Valid XHTML 1.0! Valid CSS!
Page created in 0.257 seconds with 18 queries.