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Topic: Calculating pH of H20  (Read 10926 times)

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Offline lucasloredo

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Calculating pH of H20
« on: January 14, 2007, 05:18:38 PM »
The problem reads as follows:

Calculate the pH of each of the following solutions.
a.) 0.100 M propanoic acid (HC3H5O2, Ka = 1.3 X 10-5)
b.) 0.100 M sodium propanoate (NaC3H5O2)
c.) Pure H2O
d.) A mixture containing 0.100 M HC3H5O2 and 0.100 M NaC3H5O2

I've gotten a & b already (the first was easy, just plug and chug basically, then part b was slightly more difficult, having to find the Kb of the reaction then going through the regular motions). However, I can't figure out how to get part C. I have the values here if anyone wants to use them:

For part a.) [H+] = 1.13X10-3 and the pH = 2.95
For part b.) [OH-] = 8.77X10-6 and the pH = 8.94

The only thing I could think of for part C was to take the two equations:

HC3H5O2 <-----------> H+ + C3H5O2-
C3H5O2- <-----------> HC3H5O2 + OH-

Then cancel out the like terms on each side to give you
H2O <---------> H+ + OH-

But I'm stuck from there  ???

Any help would be appreciated!

Thanks,
Lucas

Offline Borek

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Re: Calculating pH of H20
« Reply #1 on: January 14, 2007, 05:27:43 PM »
You really don't know what is pH of pure water? That's one of the most basic things about pH scale. You have confused yourself as hell :)
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Offline lucasloredo

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Re: Calculating pH of H20
« Reply #2 on: January 14, 2007, 05:48:32 PM »
Haha yes of course i know the pH is going to be 7.00, however we must prove so. That's why I'm stuck!  :P

Offline Borek

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Re: Calculating pH of H20
« Reply #3 on: January 14, 2007, 06:38:08 PM »
Square root of Kw.
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Offline lucasloredo

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Re: Calculating pH of H20
« Reply #4 on: January 14, 2007, 07:20:36 PM »
Right . . . but don't you think part C. would have to do with the rest of the problem? Like I have to use some of that data to somehow prove the pH of water is 7? Maybe I'll just leave it blank until we talk about it in school ...

Offline enahs

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Re: Calculating pH of H20
« Reply #5 on: January 14, 2007, 07:39:03 PM »
http://www.science.uwaterloo.ca/~cchieh/cact/applychem/waterchem.html
Look at the autoionization of water section. And just search google with that term for more examples.

Offline english

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Re: Calculating pH of H20
« Reply #6 on: January 14, 2007, 08:26:50 PM »
You really don't know what is pH of pure water? That's one of the most basic things about pH scale. You have confused yourself as hell :)

LOL

Offline jennielynn_1980

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Re: Calculating pH of H20
« Reply #7 on: January 16, 2007, 10:19:48 AM »
Here is some info I used to get me started on a simliar question
One molecule in one million will ionize in water at 25 C and
[H+] = [OH-]
and in water [H+] = 1.00 x 10-7

Hope that helps

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