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Topic: Equilibrium Calculations from Kc with a cubic equation  (Read 4370 times)

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Offline RMGC

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Equilibrium Calculations from Kc with a cubic equation
« on: March 05, 2007, 03:52:24 PM »
Im really lost on this one:  1 mol of CO and 3mol of H2 are placed in a 10L vessel at 1200K. 
The reaction is CO(g) + 3H2(g) <-----> CH4(g) + H2O(g).   The Kc is 3.92.

Using Stochiochemistry and the formula for Kc I determined 3.92=(x2)/(.1-x)(.3-3x)3.  Im not the greatest at math and was having trouble solving for x.  Please help

Offline xiankai

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Re: Equilibrium Calculations from Kc with a cubic equation
« Reply #1 on: March 06, 2007, 07:27:16 AM »
it is easiest to take volume out of the equation first, so that you can deal with moles only.

since c = n/v,

Kc = [CH4][H2O]/[H2]3[CO]
= {CH4}{H2O}/{H2}3{CO} * (1/V)-2

where let us take {A} to be the number of moles of A. and V to be the volume of the system.

so we have 3.92 = x2/(1-x)(3-3x)3.

im not sure if your method works fine, though since i never particularly paid much attention to my physical chemistry lectures and i prefer my method any day, its your choice.  :P

now for the mathematical part... (im using my formula, you could change it to yours without much difficulty i should think)

3.92 = x2/(1-x)(3-3x)3
3.92 = x2/(1-x)(1-x)3(3)3
105.84 = x2/(1-x)4
10.29 = x/(1-x)2
10.29 = x/(1-2x+x2)
10.29 -20.58x + 10.29x2 = x
10.29x2 -21.58x +10.29 = 0

you can solve the quadratic equation henceforth...
one learns best by teaching

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