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Topic: Ka, Kb  (Read 4375 times)

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bird8584

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Ka, Kb
« on: March 24, 2005, 01:06:59 PM »
the pH of a .0243 M solution of a monoprotic weak acid is 2.56.  What is Ka for the acid?

I don't understand this problem.

   HA        = A-    +    H+
.0234-x      0+x       .00275 +x


pH=2.56 [H+]=10^-2.56=.00275

Demotivator

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Re:Ka, Kb
« Reply #1 on: March 24, 2005, 01:26:58 PM »

The statement tells you that after dissociation of HA, [H+] is .00275,  not .00275+x.
So, guess what A- and HA would have to be by stoichiometry.


Offline AWK

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Re:Ka, Kb
« Reply #2 on: March 25, 2005, 01:16:40 AM »
Quote
The statement tells you that after dissociation of HA, [H+] is .00275,  not .00275+x.

This problem needs more precise calculation
Ka=[A-][H+]/(c-[H+])
Neglecting dissociation of water: [A-] = [H+]
hence Ka=[H+]^2/(0.0243-[H+])
« Last Edit: March 25, 2005, 01:20:58 AM by AWK »
AWK

Demotivator

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Re:Ka, Kb
« Reply #3 on: March 25, 2005, 09:51:44 AM »
This problem needs more precise calculation
Ka=[A-][H+]/(c-[H+])
Neglecting dissociation of water: [A-] = [H+]
hence Ka=[H+]^2/(0.0243-[H+])
That's exactly what I was implying!  ::)
« Last Edit: March 25, 2005, 11:47:52 PM by Demotivator »

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