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Topic: equilibrium and concentrations  (Read 3782 times)

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Offline autum_leaves

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equilibrium and concentrations
« on: March 02, 2009, 01:08:12 PM »
Here is my question...

When heated, carbon monoxide reacts with water according to the equation

CO (g) + H20 (g)  ::equil:: CO2 + H2

The value of equilibrium constant for this reaction is 3.2 at 700o C. What will the concentrations of all gases at equilibrium, when 5.00 mol of CO and 5.00 mol of H2O are mixed in a 2.0L reactor and heated to 700o C?

Step 1#

CO= 5.00 mol / 2.00 L = 2.5M
H2O = 5.00 mol / 2.00 L = 2.5 M

Step 2: ICE table

        CO (g) + H20 (g)  ::equil:: CO2 + H2
I:     2.5          2.5                      0                          0
C:    -x            -x                        x                          x
E:   2.5-x         2.5-x                    x                          x


And this is where I get stuck. Am I suppose to use the quadratic equation here? if so I am coming up with a cube (not right)

Any suggestions will *delete me*! 

Also I have looked at other examples of this type of question and the M of one of the products is usually given!!

So confused ???

Offline sjb

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Re: equilibrium and concentrations
« Reply #1 on: March 02, 2009, 01:22:03 PM »
So from your "E" line, what is the expression for K?

I don't see where you're getting a cubic equation from at a first glance.

Offline autum_leaves

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Re: equilibrium and concentrations
« Reply #2 on: March 02, 2009, 01:40:42 PM »
nevermind about the cube i thought I would get.
I redid the equation. made a "simple" mistake !!

but now I am coming up with x = 8.36M

This seems like a really high number for this equation

any suggestions

Online Borek

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Re: equilibrium and concentrations
« Reply #3 on: March 02, 2009, 02:26:19 PM »
Show your equation, check you math.
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Offline autum_leaves

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Re: equilibrium and concentrations
« Reply #4 on: March 02, 2009, 04:35:00 PM »
3.2= x2/ x2-5.00x +6.25 

3.2(x2-5.00x+6.25 = x2

2.2x2-16x + 20 = 0

and from there I do the quadratic eq. and end up with

16 +or- 20.8 / 4.4

can't use the neg so my answer is x = 8.36

This question is truly difficult..

Online Borek

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Re: equilibrium and concentrations
« Reply #5 on: March 02, 2009, 04:53:35 PM »
and from there I do the quadratic eq. and end up with

16 +or- 20.8 / 4.4

Check your math.

2.2*8.362-16*8.36+20=40
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