April 25, 2024, 05:42:43 AM
Forum Rules: Read This Before Posting


Topic: is this 2 isomer of dimethylcyclopropane optically active ?  (Read 5808 times)

0 Members and 1 Guest are viewing this topic.

Offline sahar58

  • Regular Member
  • ***
  • Posts: 11
  • Mole Snacks: +0/-0
is this 2 isomer of dimethylcyclopropane optically active ?
« on: January 27, 2010, 02:15:15 AM »
is equal mixture of cis-1,2-dimethyl cyclopropane and trans-1,2-dimethyl cyclopropane optically active?


i know that cis-1,2-dimethyl cyclopropane is achiral and is not optically active but what will happen if have equal mixture with trans-1,2-dimethyl cyclopropane?

and what about equal mixture of S,S-trans-1,2-dimethyl cyclopropane and R,R-trans-1,2-dimethyl cyclopropane?

they are enantiomer, so can rotate polrized plane but in opposite direction. is my statement correct?


Offline AWK

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 7979
  • Mole Snacks: +555/-93
  • Gender: Male
Re: is this 2 isomer of dimethylcyclopropane optically active ?
« Reply #1 on: January 27, 2010, 10:40:05 AM »
Hint: racemate
AWK

Offline sahar58

  • Regular Member
  • ***
  • Posts: 11
  • Mole Snacks: +0/-0
Re: is this 2 isomer of dimethylcyclopropane optically active ?
« Reply #2 on: January 28, 2010, 12:47:51 AM »
Hint: racemate

az i know racemate, is one that has equal amounts of left- and right-handed enantiomers of a chiral molecule.

but this 2 conformation are not enantiomers and cis isomer is not chiral, too.

i guess that this mixture has optical activity, because of chiral trans.
?

Offline AWK

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 7979
  • Mole Snacks: +555/-93
  • Gender: Male
Re: is this 2 isomer of dimethylcyclopropane optically active ?
« Reply #3 on: January 28, 2010, 02:44:30 AM »
Mixture of trans isomers forms a racemate (default). Otherwise you should specify isomer RR or SS.
AWK

Sponsored Links