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Author Topic: stereochemistry of sulfinimine  (Read 1856 times)

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miro_2k

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stereochemistry of sulfinimine
« on: July 10, 2011, 07:52:35 AM »

hey guys
i was reading a topic about asymmetric synthesis of amines, using enantiopure of sulfinimine , it is nice topic but i was wondering where the stereogenic centre of sulfinimine lol . is it the nitrogen or Sp2 carbon of imine ( i am talking about absolute configuration R , and S)
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Dan

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Re: stereochemistry of sulfinimine
« Reply #1 on: July 10, 2011, 01:47:13 PM »

No, on S (probably, you have not provided a structure). The stereogenic centre on S of sulfimides is analogous to the chirality of sulfoxides.
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