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Offline flaren5

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Equilibrium Concentration Question??
« on: July 05, 2012, 01:00:46 PM »
Good day all,  I am ineed of some help on the following question.  I thought I was understanding these types of question but now I seem to be confused.  Any help is greatly appreciated.

Question:

The decompostion of N2O4 at 298K,

N2O4(g) <--->  2NO2 (g)

has Kc=4.61x10^-3.  A 2.00L vessel contained 0.0466 mol N2O4 at equilibrium. Calculate the concentration of NO2 in the vessel.
« Last Edit: July 05, 2012, 01:38:37 PM by flaren5 »

Offline sjb

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Re: Equilibrium Concentration Question??
« Reply #1 on: July 05, 2012, 01:23:55 PM »
Good day all,  I am ineed of some help on the following question.  I thought I was understanding these types of question but now I seem to be confused.  Any help is greatly appreciated.

Question:

The decompostion of N2O4 at 298K,

N2O4(g) <--->  2N2O2 (g)

has Kc=4.61x10^-3.  A 2.00L vessel contained 0.0466 mol N2O4 at equilibrium. Calculate the concentration of NO2 in the vessel.

NO2, presumably, not N2O2? What is your expression for Kc?

Offline flaren5

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Re: Equilibrium Concentration Question??
« Reply #2 on: July 05, 2012, 01:37:50 PM »
Oooops...I did make a mistake when inputing the info...the following question is the CORRECT information.

Question:

The decompostion of N2O4 at 298K,

N2O4(g) <---> 2NO2 (g)                    Kc=4.61x10^-3. 

A 2.00L vessel contained 0.0466 mol N2O4 at equilibrium. Calculate the concentration of NO2 in the vessel.

Thank you for any insight!!

Offline fledarmus

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Re: Equilibrium Concentration Question??
« Reply #3 on: July 05, 2012, 02:42:04 PM »
How would you start? For example, what does the equilibrium constant tell you about the relative concentrations of your materials?

Offline flaren5

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Re: Equilibrium Concentration Question??
« Reply #4 on: July 05, 2012, 02:48:40 PM »
I'm not too sure how to start.  I was thinking that i was to use an ICE table, and then plug the Kc into the equation.  I'm literally at a hault on how to proceed with this question.  If I had a similar question to refer to then I probably would be able to figure it out.  Unfortunately I'm dumbfounded!!  ???

Offline Borek

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Re: Equilibrium Concentration Question??
« Reply #5 on: July 05, 2012, 04:02:18 PM »
Write formula for Kc.

What is concentration of N2O4?

What is known?

What is unknown?

How many unknowns?

Yes, it is THAT simple.
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Offline flaren5

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Re: Equilibrium Concentration Question??
« Reply #6 on: July 05, 2012, 04:28:45 PM »
Thank you...as per usual with me I was trying to make something so simplistic into something so complicated. 
I believe that I have figured it out, with your help of course.  If I understood correctly then the answer I got for NO2 concentration is 1.04 x 10^-2.

Does this sound possible?

Offline Borek

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Re: Equilibrium Concentration Question??
« Reply #7 on: July 05, 2012, 04:33:28 PM »
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