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Topic: ChemB - Vapor Pressure above Soln, Help appreciated.  (Read 2318 times)

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Offline spKelpDiver

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ChemB - Vapor Pressure above Soln, Help appreciated.
« on: August 31, 2012, 05:21:56 PM »
A solution contains naphthalene (C10H8)dissolved in hexane (C6H14)  at a concentration of 14.59% naphthalene by mass. Calculate the vapor pressure at 25C  of hexane above the solution. The vapor pressure of pure hexane at 25C  is 151 torr .

It has to be the summer, because this problem shouldn't have me stumped. I know the equation is PsolnsolventPsolvent.

I am having trouble pulling the mole fraction of the solvent (hexane) out of the percent by mass relationship. I know there are 14.59g (C10H8)/100g solution. I know this is relatively easy, but I am stumped. Can anybody help me see the way here?

I know that a mol fraction has to add up to 1. I tried subtracting .1459 from 1 = .8541. I then multiplied that by 151. Mastering chemistry told me I was close but wrong, and to check my calculations for sig fig errors.

Offline Borek

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Re: ChemB - Vapor Pressure above Soln, Help appreciated.
« Reply #1 on: August 31, 2012, 05:37:49 PM »
If there is 14.59g of naphthalene in 100g of the mixture, how many grams of hexane are there?
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Offline spKelpDiver

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Re: ChemB - Vapor Pressure above Soln, Help appreciated.
« Reply #2 on: August 31, 2012, 05:45:52 PM »
85.41...seriously, the summer has made me rusty! I was overthinking it. I just got it. 135 torr. Thanks for the *delete me*

Offline spKelpDiver

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Re: ChemB - Vapor Pressure above Soln, Help appreciated.
« Reply #3 on: August 31, 2012, 05:47:17 PM »
*delete me* ? LOL! First post and I am already beginning to understand the way things work around here.

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