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Topic: Equlibrium question.  (Read 4520 times)

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ReVeR

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Equlibrium question.
« on: January 26, 2006, 01:03:15 PM »
Hello.
I got the following querstion:
We have a reaction
2NCl3<->N2 +3Cl2
We have Kc=3.3e-12.
We also have 4.6e-4 mol/l of N2 present at equalibrium. THe question is how much NCl3 was in the flask initialy.
I did the following:
3.3e-12=(27 * (4.6e-4))/y^2  
After i solve for y i get 1.2, the answer is 6e-5.
Any ideas where i made the mistake?

dolphinsiu

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Re:Equlibrium question.
« Reply #1 on: January 27, 2006, 09:01:32 AM »
What is e ?

Offline Borek

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Re:Equlibrium question.
« Reply #2 on: January 27, 2006, 10:23:15 AM »
Way of expressing numbers in the so called scientific notation.

3.2e-5 = 3.2*10-5

Every calculator displays numbers this way.
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Re:Equlibrium question.
« Reply #3 on: January 29, 2006, 04:32:21 AM »
2 NCl3 <-> N2 +3 Cl2
Kc=3.3E-12.
Kc = [[ N2 ]] [[ Cl2 ]] 3 / [[ NCl3 ]] 2

NCl3     N2 Cl2
InitialX0     00
Change-2x     +x+x
Equilibrium(X0 - 2x)     (4.6E-4)x

Using the ICE table above,
x = 4.6E-4

Remembering that Kc is expressed in terms of concentration, you must convert the quantity of each substance into its corresponding concentration, before plugging into the Kc expression.

Upon algebraic manipulation, you will be able to find X0, ie. the initial amount of NCl3 initially present in the flask.
« Last Edit: January 29, 2006, 04:34:24 AM by geodome »
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