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Topic: NO2 deactivating group question  (Read 1189 times)

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Offline Mark S 2014

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NO2 deactivating group question
« on: April 15, 2014, 05:16:34 PM »
My textbook doesn't seem to show the NO2 group exerting a -M effect upon the carbocation when a new substituent group is attached to nitrobenzene. It simply shows that it meta-directs because it is the only position that does not allow the positive charge to be at the 1 position. It shows resonance withdrawing electrons away from the ring BEFORE it is substituted, should it not show how resonance effects the carbocation when the new sub group is attached too ?

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