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Topic: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?  (Read 3870 times)

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Offline Bill321

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I tried to look for any relevant literature, but had no luck. Can someone please help? Thanks

Offline Arkcon

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Re: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?
« Reply #1 on: July 25, 2014, 01:16:29 PM »
Well, this is more of a general chemistry question, instead of a nuclear chemistry question.  So, I don't know what your literature sources are likely to be.  Can you begin to answer this question for your self?  Start with what sort of reaction are you expecting -- double replacement, or red-ox?  Can you compare the electronegativities of uranium and cobalt?  See if that gives you a hint?
« Last Edit: July 25, 2014, 04:32:17 PM by billnotgatez »
Hey, I'm not judging.  I just like to shoot straight.  I'm a man of science.

Offline Enthalpy

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Re: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?
« Reply #2 on: July 25, 2014, 02:23:47 PM »
UO2 is an obstinate solid. Under what conditions does CoF3 come in contact? A furnace?

Offline gippgig

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Re: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?
« Reply #3 on: July 25, 2014, 10:14:47 PM »
CoF3 is a strong fluorinating agent. I would expect (educated guess) it to form uranyl fluoride:
UO2 + 2CoF3 = UO2F2 + 2CoF2.

Offline Bill321

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Re: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?
« Reply #4 on: July 26, 2014, 12:11:09 AM »
Thank you all for your responses.
I was trying to set up a laser fluorination system. Want to get Oxygen out of UO2. Not sure if it will form UF6+O2+Co.
Any input would greatly be appreciated.

Offline Bill321

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Re: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?
« Reply #5 on: July 26, 2014, 12:14:07 AM »
Hi Enthalpy,
The reaction will be in a vacuum chamber, heated with CO2 laser.

Offline Arkcon

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Re: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?
« Reply #6 on: July 26, 2014, 05:46:14 AM »
Hmmm  ... tricky.  OK, I'm first wondering what sort of vapor density you can get from UO2.  Like Enthalpy: said, that's practically a refractory material.  DOes a CO2 laser really impart sufficient thermal energy to vaporize anything?  If so, how are the products stable in vapor phase?  And freely reduced cobalt metal -- that really doesn't sound plausible to me.  But we should keep this thread alive so experts can weigh in.
Hey, I'm not judging.  I just like to shoot straight.  I'm a man of science.

Offline Bill321

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Re: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?
« Reply #7 on: July 26, 2014, 01:21:33 PM »
Yes, Arkon,
These are the questions I want to know the answers before I can actually start the project.
Following gippgig's perspective, it would work if the following reaction happens:
UO2 + 2CoF3 = UF4 + 2CoF2 + O2.

yes, CO2 laser will used as laser ablation.

Offline Enthalpy

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Re: Can Uranium oxide (UO2) react with Cobalt trifluoride (CoF3 )?
« Reply #8 on: July 28, 2014, 09:54:00 AM »
No worries with CO2 lasers. Just pick the proper model and concentrating optics. They're used to cut steel sheets and plates.

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