April 26, 2024, 11:04:33 AM
Forum Rules: Read This Before Posting


Topic: Ideal solution  (Read 1885 times)

0 Members and 1 Guest are viewing this topic.

Offline tvtokyo

  • Regular Member
  • ***
  • Posts: 18
  • Mole Snacks: +0/-2
Ideal solution
« on: October 19, 2014, 12:47:43 AM »
Hi some question on ideal solution. Do help thanks!
Qn:
Lets say a solution contain ethanol and choloroform.
Mole fraction of chloroform in solution = 0.990
The vapour in equilibrium with the solution has a pressure of 438.6 torr.
Mole fraction of choloroform in the vapour = 0.979.

(i) Calculate the partial pressure of each component in the vapour phase

Is it
P (chloroform) = 0.979*438.6 = 429 Torr
P (ethanol) = 438.6-429 = 9.21

(ii) The vapour pressure of pure choloroform
According to Raoult's law
P* (chloroform) = 429/0.990 = 433 Torr

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27664
  • Mole Snacks: +1801/-410
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Ideal solution
« Reply #1 on: October 19, 2014, 03:42:00 AM »
Looks OK to me.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline mjc123

  • Chemist
  • Sr. Member
  • *
  • Posts: 2053
  • Mole Snacks: +296/-12
Re: Ideal solution
« Reply #2 on: October 19, 2014, 06:57:16 PM »
How does 438.6 - 429 = 9.21?
Oh, it's because 0.979*438.6 = 429.39
Leave the decimal places in and round off the answer at the end.

Sponsored Links