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Topic: balancing redox reaction (basic)  (Read 1928 times)

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Offline johnnyjohn993

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balancing redox reaction (basic)
« on: October 22, 2014, 03:42:00 AM »
NH2OH + CO2 =N2 + CO  (BASIC)

2OH- +2H+ +CO2 = CO + H20  + 2OH-

2e- + H2O + CO2 = CO + 2OH-


3OH- +H2O + 2NH2OH = N2 + 5H+ +5OH-

2OH- +H2O + 2NH2OH = N2 + 5H2O

2OH- + 2NH2OH= N2 +4H2O + 2e-
2e- + H2O + CO2 =CO + 2OH-

ANSWER: 2NH2OH + CO2 = N2 + 3H2O + CO

QUESTIONs :
1)why did we add H2O to the side of 2NH2OH of our half reaction instead
placing it on the oxygen and hydrogen deprive N2 ?(isn't that how we do it? ).

2.)Does its always have to be alternate " that is, adding  your H+ to the CO2 half reaction; and H+ to left side of the NH2OH half reaction ? I got the answer after 30mins T_T it was so confusing though.

3) Do we have cases like we will "add up" our H2O or OH-  because we cannot cancel them ?








Offline Hunter2

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Re: balancing redox reaction (basic)
« Reply #1 on: October 22, 2014, 04:18:06 AM »
If the process works in alcaline condition then its not allowed to add H+

Correct is this:

Oxidation: 2 NH2OH  + 2OH- => N2 + 4 H2O + 2 e-

Reduction: CO2 + H2O + 2 e-=> CO + 2 OH-

Addition gives

2 NH2OH + CO2 => N2 + CO + 3 H2O

Recipe alcaline condition:

Reduction: add water on edukt side and get OH- on product side

Oxidation: add OH- on edukt side and get water on product side



acidic condition:

Reduction : add H+ on edukt side and get water on product side

Oxidation : add water on edukt side and get H+ on product side

This works every time if oxygen is in the compounds.

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