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Topic: Isothermal and reversible reactions  (Read 1719 times)

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Offline katie_nanook

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Isothermal and reversible reactions
« on: November 24, 2014, 10:28:36 AM »
OK so, I'm quite bad at physical chemistry and need some help for my exams coming up.
Can someone help me with this question?  :-\

1 mole of nitrogen gas at 250 K is compressed isothermally and reversibly from an initial volume of 24 dm^3 to a final volume of 4 dm^3. Assuming the gas obeys the ideal gas equation calculate ΔH, the increase in enthalpy of the gas.

Answer has no units.

I know the answer is zero, but why??  ???

Offline cseil

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Re: Isothermal and reversible reactions
« Reply #1 on: November 24, 2014, 02:04:02 PM »
For an isothermal transformation, ΔU is always 0 since U depends only on temperature.
ΔH = ΔU + ΔPV = ΔU + RnΔT.

ΔT is 0 so ΔH = 0.

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