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Topic: Trying to determine rate constant from lab  (Read 2160 times)

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Offline Khem

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Trying to determine rate constant from lab
« on: March 31, 2015, 02:04:11 AM »
Hi everyone,

During a recent lab, I added 5 mL of [0.8] KI to a reaction solution of 13 mL H2O, 6 mL of H2O2, and 1 mL of [0.2] NaOH.

I've been trying to figure out the molarity of I- accounting for dilution when KI was added to the solution...do you know how to do this? If you could show me, you d be a tremedous help to this undergrad!

If you need more info, please let me know.

In context: I have a first order reaction in I- and the formula I'm working with is:

K=K'/[I-] where K' is -0.1238.

Thanks so much!

Offline sjb

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Re: Trying to determine rate constant from lab
« Reply #1 on: March 31, 2015, 02:43:27 AM »
Hi everyone,

During a recent lab, I added 5 mL of [0.8] KI to a reaction solution of 13 mL H2O, 6 mL of H2O2, and 1 mL of [0.2] NaOH.

I've been trying to figure out the molarity of I- accounting for dilution when KI was added to the solution...do you know how to do this? If you could show me, you d be a tremedous help to this undergrad!

If you need more info, please let me know.

In context: I have a first order reaction in I- and the formula I'm working with is:

K=K'/[I-] where K' is -0.1238.

Thanks so much!

What is the definition of molarity?

Offline Khem

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Re: Trying to determine rate constant from lab
« Reply #2 on: March 31, 2015, 03:08:21 AM »
Molarity being the molar concentration of I-, or [I-].

Offline sjb

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Re: Trying to determine rate constant from lab
« Reply #3 on: March 31, 2015, 05:41:27 AM »
Molarity being the molar concentration of I-, or [I-].

How is molar concentration calculated?

Offline Khem

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Re: Trying to determine rate constant from lab
« Reply #4 on: April 01, 2015, 01:18:30 AM »
I would divide moles over liters, in which case I imagine I need to convert mL to liter for some component   ???


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