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Topic: Pinnick Oxidation  (Read 3083 times)

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Offline AlphaScent

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Pinnick Oxidation
« on: May 12, 2015, 02:01:08 PM »
Does anyone have a well tested procedure?  I have the original paper by Pinnick.  Just wondering if someone has a reference for a scavenger other than 2-methyl-2-butene that works well.

Cheers
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Offline AlphaScent

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Re: Pinnick Oxidation
« Reply #1 on: May 12, 2015, 04:53:23 PM »
Actually found a reference using oxone in DMF.  May try that.

Cheers
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Offline phth

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Re: Pinnick Oxidation
« Reply #2 on: May 13, 2015, 03:50:43 AM »
Like you pointed out, alter the oxidant not the scavenger.  There are alternative possibilities that may not require a scavenger/oxidant-scavenger combo that works.
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Offline AlphaScent

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Re: Pinnick Oxidation
« Reply #3 on: May 13, 2015, 09:58:16 AM »
I agree.  It is a transformation I have never done.  If I am going to an acid it is usually from an alcohol.
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