April 16, 2024, 04:15:22 AM
Forum Rules: Read This Before Posting


Topic: Errata of Physical Chemistry by Peter Atkins 10th edition  (Read 6521 times)

0 Members and 1 Guest are viewing this topic.

Offline simonsci

  • Regular Member
  • ***
  • Posts: 18
  • Mole Snacks: +0/-0
Errata of Physical Chemistry by Peter Atkins 10th edition
« on: June 19, 2015, 03:20:30 AM »
Hello, in pp. 46 of the book, I found that the author wrote 'Because the molar volume of a perfect gas is equal to RT/p, an
equivalent expression is Z=RT/pVm ° , which we can write as...', should the expression 'Z=RT/pVm °' be changed to 'pVm/RT'? Or did I made a mistake? :(

Offline mjc123

  • Chemist
  • Sr. Member
  • *
  • Posts: 2053
  • Mole Snacks: +296/-12
Re: Errata of Physical Chemistry by Peter Atkins 10th edition
« Reply #1 on: June 19, 2015, 08:32:28 AM »
My second edition says Z = pVm/RT, so it looks like a mistake, but better check that yours is not using a different definition. Check the definition of Z, is it consistent with that expression, and is that expression consistent with others in the chapter/book? Is there a graph or table of values? My graph shows Z, as I've defined it, increasing monotonically with pressure for H2 at 0°C, while for methane, ethene and ammonia it first decreases then increases. Your definition of Z would turn it upside down.

Tenth edition. That makes me feel old!

Offline simonsci

  • Regular Member
  • ***
  • Posts: 18
  • Mole Snacks: +0/-0
Re: Errata of Physical Chemistry by Peter Atkins 10th edition
« Reply #2 on: June 21, 2015, 02:56:53 PM »
Another typo in the book is in pp. 86.  >:(

Offline mjc123

  • Chemist
  • Sr. Member
  • *
  • Posts: 2053
  • Mole Snacks: +296/-12
Re: Errata of Physical Chemistry by Peter Atkins 10th edition
« Reply #3 on: June 21, 2015, 05:48:47 PM »
Are you going to enlighten us? We don't all have it to hand, you know.

Offline Harshal

  • Very New Member
  • *
  • Posts: 1
  • Mole Snacks: +0/-0
Errata of Physical Chemistry by Peter Atkins 10th edition
« Reply #4 on: October 02, 2017, 05:16:34 AM »
On page 97, in Table 2D.2*, three data values are incorrectly shifted to the adjacent left column, namely - Tb /K for CO2 is printed as +1.10, whereas it should be kept blank. So actually μ/(K bar-1) for will be +1.10.
Similarly Tf/K for He is printed as 4.2. It should be printed in the next column for Tb/K.
And lastly, the value -0.060 printed in Tb/K for CO2 should be 4.2 as mentioned above, and μ/(K bar-1) for He should be -0.060.
All other values are in correct place, I believe.
Above correction based on the Resource section, page 979, Table 2D.2,
in the same book.
- Best Regards,
  H K.



Sponsored Links