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Preventing Ketone reacting with itself
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Topic: Preventing Ketone reacting with itself (Read 1732 times)
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Unco
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Preventing Ketone reacting with itself
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on:
August 04, 2015, 08:46:43 PM »
Hi all, I am currently running a reaction which requires me to deprotonate a ketone, what are some ways/techniques that would minimize the deprotonated ketone reacting with the protonated ketone in the reaction vessel?
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clarkstill
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Re: Preventing Ketone reacting with itself
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Reply #1 on:
August 05, 2015, 12:12:23 PM »
A classic way (courtesy of Stork) is to make the enamine:
http://pubs.acs.org/doi/pdf/10.1021/ja00885a021
http://www.scripps.edu/baran/images/grpmtgpdf/Lockner_Nov_07.pdf
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Unco
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Re: Preventing Ketone reacting with itself
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Reply #2 on:
August 05, 2015, 10:14:46 PM »
thank you for the links!
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Preventing Ketone reacting with itself