April 19, 2024, 09:38:32 PM
Forum Rules: Read This Before Posting


Topic: Silver/Silver chloride reference electrode  (Read 1654 times)

0 Members and 1 Guest are viewing this topic.

Offline lip

  • Regular Member
  • ***
  • Posts: 39
  • Mole Snacks: +0/-0
Silver/Silver chloride reference electrode
« on: January 19, 2016, 01:42:52 PM »
When potential is measured by using silver/silver chloride electrode, Ag+ would precipitate from the solution (as Ag).  This will increase the equilibrium [Cl-]( negligibly small increase ). So half cell potential of the electrode should change right  ? so in what sense we consider E of this electrode to remain to be constant and thereby use this as a reference  electrode ? or stability of reference electrode is just a relative term ?

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27652
  • Mole Snacks: +1800/-410
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Silver/Silver chloride reference electrode
« Reply #1 on: January 19, 2016, 02:07:26 PM »
Yes, technically the potential is not stable, but it is perfectly stable in practical terms. In typical case electrode (Ag wire covered with AgCl) is immersed in 1 M (or comparable concentration) solution of KCl. As long as the electrode is used only as a reference currents flowing through it are so low, changes in the concentration of Cl- are completely negligible.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline lip

  • Regular Member
  • ***
  • Posts: 39
  • Mole Snacks: +0/-0
Re: Silver/Silver chloride reference electrode
« Reply #2 on: January 25, 2016, 02:54:28 PM »
Ok. Thanks Borek

Sponsored Links