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Topic: addition reaction  (Read 1688 times)

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Offline koolman

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addition reaction
« on: May 23, 2016, 01:55:53 PM »
We have to find the compound C .
Why the product I formed is wrong and how is the correct product is formed .

Offline spirochete

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Re: addition reaction
« Reply #1 on: May 23, 2016, 04:06:36 PM »
I would start by drawing the correct lewis structure for the alpha beta unsaturated ester.

Also as a general rule you should not expect a bond to silver in the major organic product of a reaction. Ag+ is much more likely to be essentially a spectator, or perhaps a lewis acid in the mechanism. Overall you can probably safely ignore it, except for the fact that it tells you fluorine is an anion.

Offline koolman

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Ar substitution
« Reply #2 on: May 24, 2016, 10:43:14 AM »
in the following reaction we have to find the major product .

according to me it will be C compound beacuse of anion (intermediate) stability.

Offline koolman

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relative rate of solvolysis
« Reply #3 on: May 25, 2016, 08:33:22 AM »
Among the following compounds I think D compound has more rate of solvolysis in 50% aq.ethanol at 45°C than compound C .
Due to more resonance.
But the compound C has more rate . Why?

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