For the separation in a) I guess evaporation will be the technique used.
You are not wrong, but to speed things up we usually use distillation. However, if you want pure, large CuSO
4 crystals, crystallization is more preferrable.
b). Electrolysis of Cu (copper) from Copper sulfate
What do you want help with this question? If you want the procedure or experimental set-up of it, just look them up on Google.