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Topic: Finding molarity through density  (Read 2165 times)

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Offline galpinj

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Finding molarity through density
« on: September 20, 2016, 11:41:19 PM »
Question is as follows:

A solution contains 10% HCl by mass in water. What is the molarity of the solution? The molar mass of HCl is 36.45 g/mol and the density of HCl is 1.05 kg/L

The answer is 2.88 M  (10/100)(1/36.45)(1.05)(1000)

I do not understand why we need to use the density of HCl when solving this question. Can't we just do the following:

(10 g of HCl / 100 g water)(1 mole HCl / 36.45 g HCl)(1 g H2O/1 mL H2O)(1000 mL H2O/1 L H2O). Wouldn't this give us the molarity for HCl?

Edit: Even if we exchanged 100 g water for 100 g solution, I don't know how we could cancel it out with density. Isn't density for HCl they provided literally kg HCl / L HCl?

Offline sjb

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Re: Finding molarity through density
« Reply #1 on: September 21, 2016, 02:27:19 AM »
Question is as follows:

A solution contains 10% HCl by mass in water. What is the molarity of the solution? The molar mass of HCl is 36.45 g/mol and the density of HCl is 1.05 kg/L

The answer is 2.88 M  (10/100)(1/36.45)(1.05)(1000)

I do not understand why we need to use the density of HCl when solving this question. Can't we just do the following:

(10 g of HCl / 100 g water)(1 mole HCl / 36.45 g HCl)(1 g H2O/1 mL H2O)(1000 mL H2O/1 L H2O). Wouldn't this give us the molarity for HCl?

Edit: Even if we exchanged 100 g water for 100 g solution, I don't know how we could cancel it out with density. Isn't density for HCl they provided literally kg HCl / L HCl?

What is the definition of density?

Offline Borek

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Re: Finding molarity through density
« Reply #2 on: September 21, 2016, 02:40:37 AM »
the density of HCl is 1.05 kg/L

Poor wording. This is not density of the HCl, this is density of the HCl solution.
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Offline galpinj

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Re: Finding molarity through density
« Reply #3 on: September 22, 2016, 01:50:29 PM »
the density of HCl is 1.05 kg/L

Poor wording. This is not density of the HCl, this is density of the HCl solution.

Sjb, density is defined as mass/volume

Borek, I agree. After watching a couple of videos with similar questions, it is obvious that my equation is wrong in that it should be 10 g of HCl / 100 g of solution. This can be cancelled out if we have the density of the solution, not the density of HCl. I'm assuming that the density provided is meant to be the density of the solution.

Thank you everyone

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