April 26, 2024, 07:49:39 AM
Forum Rules: Read This Before Posting


Topic: Tollens vs. Fehling  (Read 5493 times)

0 Members and 1 Guest are viewing this topic.

Offline FeLiXe

  • Theoretical Biochemist
  • Chemist
  • Full Member
  • *
  • Posts: 462
  • Mole Snacks: +34/-7
  • Gender: Male
  • Excited?
    • Chemical Quantum Images
Tollens vs. Fehling
« on: May 26, 2006, 10:14:00 AM »
Hi, I just read that 4-Methyl-benzaldehyde will react with Tollens-reagent and not with Fehling-reagent. Could someone tell me why?

thanks
Math and alcohol don't mix, so... please, don't drink and derive!

Offline Donaldson Tan

  • Editor, New Asia Republic
  • Retired Staff
  • Sr. Member
  • *
  • Posts: 3177
  • Mole Snacks: +261/-13
  • Gender: Male
    • New Asia Republic
Re: Tollens vs. Fehling
« Reply #1 on: May 26, 2006, 10:22:59 AM »
The benzene ring provides reasonance stabilisation to the carbonyl group, thus making it more resistant to oxidation. Fehling is not as strong an oxidising agent as Tollen's
"Say you're in a [chemical] plant and there's a snake on the floor. What are you going to do? Call a consultant? Get a meeting together to talk about which color is the snake? Employees should do one thing: walk over there and you step on the friggin� snake." - Jean-Pierre Garnier, CEO of Glaxosmithkline, June 2006

Offline FeLiXe

  • Theoretical Biochemist
  • Chemist
  • Full Member
  • *
  • Posts: 462
  • Mole Snacks: +34/-7
  • Gender: Male
  • Excited?
    • Chemical Quantum Images
Re: Tollens vs. Fehling
« Reply #2 on: May 26, 2006, 04:16:40 PM »
cool, thanks
Math and alcohol don't mix, so... please, don't drink and derive!

Sponsored Links