April 19, 2024, 07:48:45 PM
Forum Rules: Read This Before Posting


Topic: hydrosilylation reaction rate comparison (second)  (Read 1538 times)

0 Members and 1 Guest are viewing this topic.

Offline craken66

  • Regular Member
  • ***
  • Posts: 20
  • Mole Snacks: +0/-1
hydrosilylation reaction rate comparison (second)
« on: June 12, 2017, 09:04:02 PM »
Hello,
Another question.
According to chalk-harrod mechanism, first rxn step is reductive addion of Si-H into Pt catalyst, and so Pt catalyst charge is changed; Pt of Karstedt's catalyst is from 0 to +2, and Pt of speier's one is from -2 to 0. So, in my opinion, Speier's catalyst will take this step easily than Karsredt's one due to electon donating property of metals. This concept is right?

Sponsored Links