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Topic: How can I calculate the pH of a solution?  (Read 2389 times)

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Offline sucrose

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How can I calculate the pH of a solution?
« on: June 09, 2017, 09:38:45 PM »
Let's say I have 2.1kg of sucrose dissolved in 1 litter of distilled water. I know the distilled water is 7 (in a vacuum where it doesn't come in contact with air). But what would the pH be once I dissolve the sucrose in the water?

Offline Arkcon

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Re: How can I calculate the pH of a solution?
« Reply #1 on: June 09, 2017, 09:46:19 PM »
You can generally use the published pKa of a molecule (or experimentally determine the pKa if the molecules is obscure) to determine the ph.  Sucrose is a tough one 'tho.  Ref: http://www.sciencedirect.com/science/article/pii/S0963996905001912
Hey, I'm not judging.  I just like to shoot straight.  I'm a man of science.

Offline sucrose

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Re: How can I calculate the pH of a solution?
« Reply #2 on: June 09, 2017, 10:03:37 PM »
Thank you. Since sucrose is problematic, let me use caffeine instead. I can see caffeine has a published pKa of 14.0 at 25C. Is there a formula I can plug this into, with the amount of caffeine and the amount of distilled water to get the pH?

Offline Borek

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Re: How can I calculate the pH of a solution?
« Reply #3 on: June 10, 2017, 03:08:07 AM »
A lot depends on the concentration, so choosing the right formula is not always simple and straightforward. Whole calculation process is explained here:

http://www.chembuddy.com/?left=pH-calculation&right=toc

Simpler approach, that ignores "why" (and effects of the solution ionic strength):

http://www.chembuddy.com/?left=BATE&right=pH-cheat-sheet

ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

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