I was recently asked about how to do this, although I don't know how accurate the pH values have to be. I checked my copy of the Beckman Handbook of Applied Chemistry. It has a section on colloidal samples, but it did not have a specific discussion of how to obtain the pH of milk. One aspect that might be problematic is that there will be milk proteins. I have heard of commercial reagents that are designed to clean electrodes onto which protein samples have been deposited. The person who wishes to do this may not have a large budget; therefore, if I can supply him with (for example) urea or whatever reagent would be most appropriate, that might be the way to go. Thoughts?