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Author Topic: Epimerisation of N-sulfinyl imine  (Read 237 times)

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mattk92

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Epimerisation of N-sulfinyl imine
« on: February 13, 2018, 10:28:36 AM »

I've got a N-sulfinyl tBu imine and am trying to epimerise the alpha centre. There is a cis-dioxolane at the moment but I'm after the trans. Anyone got any ideas?
I've tried DBU with some success but methoxide, NaHMDS seem to degrade the material
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rolnor

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Re: Epimerisation of N-sulfinyl imine
« Reply #1 on: February 13, 2018, 03:00:44 PM »

Maybe LDA?
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