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I have Extech PH220-C, which display's pH or mV. My question is: are these mV the same as ORP or is it just the raw signal from pH probe but not an actual ORP?
Technically pH meter is just a specialized voltmeter, ORP meter is just a voltmeter too. pH meter uses an ion selective electrode and is scaled not in volts, but in pH units - which are directly proportional to the electrode potential (compare http://www.ph-meter.info/pH-measurements-potentiometry ). ORP can use any electrode, usually including ion selective ones, and is scaled in volts - but converting these volts to concentration is trivial (especially taking into account fact all voltmeters made these days are digital and use some kind of microcontroller).
What i was interested in is if Volts output of the ORP probe is the same as the actual ORP value