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Topic: Calculating molecular weight of unknown by fp depression?  (Read 8458 times)

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Offline hmrobinson09

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Calculating molecular weight of unknown by fp depression?
« on: February 24, 2009, 08:16:37 PM »
Can someone help me with this?
A solution of 2.24 x 10-1g of an organic compound of unknown molecular weight in 1.664g of camphor gave a freezing point of 176.44 Celsius. The freezing point of camphor is 179.80 Celsius, and the freezing point depression constant Kf 39.7 Celsius/m. Calculate the molecular weight of the unknown.

Offline Borek

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Re: Calculating molecular weight of unknown by fp depression?
« Reply #1 on: February 25, 2009, 02:32:57 AM »
What is formula for calculation of freezing point depression?
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Offline sm2345

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Re: Calculating molecular weight of unknown by fp depression?
« Reply #2 on: February 27, 2009, 12:28:08 AM »
Here is a formula which can be used to calculate the Molecular Weight of the solute:

ΔTf = (kfxW2x1000)/(M2xW1)

where ΔTf = Depression of freezing point
       
         kf  = Molal Depression Constant(Cryoscopic constant)
     
         W2 = Weight of the solute
 
         W1 = Weight of the solvent &

         M2 = Molecular Mass of the solute.

Offline Borek

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Re: Calculating molecular weight of unknown by fp depression?
« Reply #3 on: February 27, 2009, 03:34:41 AM »
ΔTf = (kfxW2x1000)/(M2xW1)

While it is not wrong, it may be confusing, as it makes several conversions in one step, instead of concentrating on the general concept:

ΔTf = kf m

where m is molality.
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