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Chemistry Forums for Students => Organic Chemistry Forum => Topic started by: Mcant on June 04, 2013, 10:00:45 AM

Title: tert ammonium salts (ILs)
Post by: Mcant on June 04, 2013, 10:00:45 AM

Hi all I'm looking for any specific literature on synthesis of tertiary ammonium cation Ionic liquids, my target will be [NR4]+ with at least one R = Butyl side chain. with PF6- anion.

Going the route of NR3 + X-R -----> [NR4+] + X- --------> NR4+ PF6-

So quaternisation using halo alkane then metathesis / anion exchange of halide anion with PF6 (KPF6).

Anyone know of a paper (hopefully specifically with this synthesis) other wise something of a similar nature.


Thanks in advance.

Title: Re: tert ammonium salts (ILs)
Post by: BARAJAN on June 07, 2013, 07:51:15 AM

I just know these papers I hope they help

doi:10.1016/j.apcata.2009.10.008 (http://doi:10.1016/j.apcata.2009.10.008)
doi:10.1016/j.progpolymsci.2008.12.001 (http://doi:10.1016/j.progpolymsci.2008.12.001)
doi:10.1016/j.molliq.2011.09.001 (http://doi:10.1016/j.molliq.2011.09.001)