May 02, 2024, 05:06:52 PM
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Topic: How come water and potassium give potassium hydroxide and not potassium oxide?  (Read 1281 times)

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Offline thrrr

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Hello, sorry if this is too basic or anything, I'm only just starting off with whatever my country's equivalent of High School Chemistry is.

So there was a question where I had to write out potassium+water as a chemical equation. So I did:

2K + H2O :rarrow: K2O + H2

But the answer was:

2K + 2H2O :rarrow: 2KOH + H2

I asked my sister about this, and she said potassium oxide doesn't exist. But I googled it and it does. So why doesn't this reaction give potassium oxide?

Thanks.

Offline Vidya

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K2O exists as solid only
If you put it in water it reacts immediately with water to give KOH because it is a strong basic oxide.

Offline AWK

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Most chemistry textbooks treat water as a natural reaction environment (implicitly excess of water). And then the second reaction is correct.
However, from both a chemistry and stoichiometry point of view, both reactions are possible.
Depending on the precision of the question, one or both equations are the correct answer.
AWK

Offline Fudjsk

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Water in other terms can be Hydrogen Hydroxide so...

2K + 2H(OH) yields 2K(OH) + H2

Offline AWK

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Water in other terms can be Hydrogen Hydroxide so...

2K + 2H(OH) yields 2K(OH) + H2

Brackets are not needed.

In addition, this reaction is in the post of Thrrr
AWK

Offline DrCMS

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As AWK has said when potassium reacts in water the final product is potassium hydroxide.

Your initial reaction is only the 1st step of this
2K + H2O :rarrow: K2O + H2

the 2nd step is
K2O + H2O :rarrow: 2KOH

combined this gives:
2K + 2H2O :rarrow: 2KOH + H2

Given that an excess of water is always used when reacting with potassium (or other group 1 metals) the final reaction describes what is happening more completely.

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