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General Forums => Generic Discussion => Topic started by: constant thinker on March 13, 2007, 09:40:02 PM

Title: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming...
Post by: constant thinker on March 13, 2007, 09:40:02 PM
I want to pose this thought, well thoughts.

Nuclear power plants have enormous cooling towers. Those enormous cooling towers release steam, right? Well steam is water as we all know. Now wouldn't water vapor also act like a green house gas, absorbing and trapping the heat.

Hydrogen cars would theoretically release water vapor which would add to water vapor amounts in the atmosphere. Imagine every car being hydrogen powered. I'd think that in some of the major metropolitan areas, they'd wind up seeing an increase in the amount of rain that falls, and the increased water vapor could also potentially trap heat. Also in the Northeast, and places that have a winter, the water vapor coming from the hydrogen cars would probably ice up the roads. Icier roads would mean an increase in salt/deicer usage. An increase in salt/deicer usage would mean pollution from it, and an increase in municipal budgets.

Now personally I'm not sure about water vapor as a greenhouse gas, and I'm all in favor of decreasing the amount of CO2 in the atmosphere, and cutting the down on the use of fossil fuels. Hydrogen powered cars could also pose unintended consequences.

Once again to clarify my stance, I'm all for nuclear energy and the hydrogen economy. I just want to see what people can come up with for possible unintended consequences.

Note: I did not stick numbers anywhere, I'm sure that the CO2 is worse than water vapor as a green house gas.
Title: Re: Nuclear Power Plants, Hydrogen, and Global Warming
Post by: Donaldson Tan on March 13, 2007, 09:52:45 PM
I think the hydrogen economy is a science fiction. Although the hydrogen economy does not release carbon dioxide, it does not facilitate the development of a private sector specialising in carbon capture and storage (CCS).

I support the methanol economy with a gradual transition from mass usage of internal combustion technology to mass usage of electrochemical oxidation (fuel cell) technology. Existing technology is able to convert Carbon Dioxide to Methanol, which in turns create an economic incentive for CCS.
Title: Re: Nuclear Power Plants, Hydrogen, and Global Warming
Post by: Borek on March 14, 2007, 04:00:17 AM
Hydrogen cars would theoretically release water vapor which would add to water vapor amounts in the atmosphere. Imagine every car being hydrogen powered. I'd think that in some of the major metropolitan areas, they'd wind up seeing an increase in the amount of rain that falls, and the increased water vapor could also potentially trap heat. Also in the Northeast, and places that have a winter, the water vapor coming from the hydrogen cars would probably ice up the roads. Icier roads would mean an increase in salt/deicer usage. An increase in salt/deicer usage would mean pollution from it, and an increase in municipal budgets.

What is the second main product of gas combustion (apart from CO2)?
Title: Re: Nuclear Power Plants, Hydrogen, and Global Warming
Post by: constant thinker on March 14, 2007, 08:20:35 PM
Hydrogen cars would theoretically release water vapor which would add to water vapor amounts in the atmosphere. Imagine every car being hydrogen powered. I'd think that in some of the major metropolitan areas, they'd wind up seeing an increase in the amount of rain that falls, and the increased water vapor could also potentially trap heat. Also in the Northeast, and places that have a winter, the water vapor coming from the hydrogen cars would probably ice up the roads. Icier roads would mean an increase in salt/deicer usage. An increase in salt/deicer usage would mean pollution from it, and an increase in municipal budgets.

What is the second main product of gas combustion (apart from CO2)?

Our buddy water vapor. Maybe I should have added in there that more water vapor would be released than now. Correct me if I'm wrong, but there is less energy stored in H2 than in our gasoline. Therefore you need more H2. Thinking about it though, the amounts of water vapor released may be similar.

Geodome, I like the thinking on methanol. As long as we're converting CO2 into methanol, then we're theoretically completing the cycle.

P.S. I know that the hydrogen economy may not ever function.
Title: Re: Nuclear Power Plants, Hydrogen, and Global Warming
Post by: Sam (NG) on March 24, 2007, 07:07:00 PM
The hydrogen to power the cars has to come from somewhere in the first place, and assuming it's not from crude oil, a promising place is from water in the first place (if certain LARGE obstacles are overcome), so water would be being created and destroyed in a theoretical cycle.  Increasing the amount of water vapour in the atmosphere will have a warming effect though, just think of the difference between cloudy nights and clear nights in winter.  But would all this extra water fall as rain, meaning that atmospheric water levels stayed roughly the same?
Title: Re: Nuclear Power Plants, Hydrogen, and Global Warming
Post by: billnotgatez on March 24, 2007, 08:36:20 PM
Some points to ponder

Water concentration in the air, as vapor is limited.
Carbon dioxide concentration is not limited.
To get hydrogen from water takes energy.
Cooling towers produce steam but remember the first statement.
From Population Clocks the USA is 301,452,660 and the World is 6,584,389,063 at 00:31 GMT (EST+5) Mar 25, 2007 plus it is growing exponentially.
China’s carbon dioxide emissions may be greater than the USA soon or now.


Title: Hydrogen Economy Fallacy
Post by: billnotgatez on April 04, 2007, 04:52:11 AM
http://www.thenewatlantis.com/archive/15/zubrin.htm

I do not know if I totally agree with all said in this article but it is cause for reflection.
Title: Re: Hydrogen Economy Fallacy
Post by: allanf on April 04, 2007, 12:24:13 PM
It does raise some reasonable issues with the widespread use of hydrogen in cars and what-not.  But I've never been convinced that hydrogen fuel-cell cars were going to be technically feasible any time soon anyways, but mostly since it seems a little insane to pump crazy-explosive hydrogen into my car.

I have heard that in some places, such as Britain and Australia, there is talk of doing steam-reformation of coal beds in situ, reducing the environmental footprint of generating hydrogen from hydrocarbons.  But I don't know how practical that is.
Title: Re: Hydrogen Economy Fallacy
Post by: billnotgatez on April 04, 2007, 12:56:52 PM
Many so-called hydrogen fuel cells use methane / natural gas instead of pure hydrogen. They basically strip the hydrogen off of the methane molecule. I am not sure how they dispose of the one existing carbon on each molecule.
Title: Re: Hydrogen Economy Fallacy
Post by: Borek on April 04, 2007, 01:58:14 PM
mostly since it seems a little insane to pump crazy-explosive hydrogen into my car.

As if gas was safe... ;)
Title: Re: Hydrogen Economy Fallacy
Post by: allanf on April 04, 2007, 03:23:40 PM
In my defense: at least gasoline isn't a pressurized gas.  It needs to mix with air and an appropriate spark before it blows me to kingdom come. ;D
Title: Re: Hydrogen Economy Fallacy
Post by: Borek on April 04, 2007, 03:35:59 PM
Yep. But it can burn you to the white ash without exploding  :P
Title: Re: Hydrogen Economy Fallacy
Post by: allanf on April 04, 2007, 04:38:16 PM
I'd still argue that gasoline in a tank is safer in accidents than a pressurized cylinder of hydrogen, or propane for that matter.
Title: Re: Hydrogen Economy Fallacy
Post by: constant thinker on April 04, 2007, 09:36:35 PM
Quote
And when you use it, the waste product will be nothing but water—“environmental pollution will no longer be a concern.” Hydrogen will be abundant, cheap, and clean. Why settle for anything less?

Apparently the author hasn't heard of the impact DHMO (http://www.dhmo.org/) on the environment.  ;)

The whole article is very pessimistic toward the hydrogen economy, but it does do a good job at pointing out technical issues.

Why don't we just all use hamster power. I saw a car that used hamster power in a commercial once.  ;)
Title: Re: Hydrogen Economy Fallacy
Post by: allanf on April 04, 2007, 09:46:11 PM
DHMO is also a greenhouse gas!
Title: Re: Hydrogen Economy Fallacy
Post by: billnotgatez on April 04, 2007, 10:37:41 PM
DHMO is also a greenhouse gas!

Yes - but a finite one == unlike carbon dioxide which is not limited
Title: Re: Hydrogen Economy Fallacy
Post by: Yggdrasil on April 04, 2007, 11:07:14 PM
For the most part I agree with Zubrin.  There has been too much hype about hydrogen fuel and there are many scientific, engineering, and policy issues that have to be worked out before a hydrogen economy could be implemented.  One technology Zubrin ignores, however, is solid-state storage of hydrogen, for example, in the form of metal hydrides.  Solid-state storage of hydrogen offers the possibility to solve the issues pertaining to the safe storage and transport of hydrogen fuel. 

Of course, the technology is nowhere near adequate.  Solid-state storage technologies are currently too slow to recharge, too expensive to produce, and too heavy to transport efficiently.  However, these problems are not insurmountable as new research could improve the technologies to the point where they are commercially feasible.  Although this is a big if, this is still an area of research which shows promise and deserves the funding its getting.

Hydrogen production, as noted by Zubrin, is the more fatal flaw of a hydrogen economy.  However, some promising research is going on in this area, for example, in the biological production of hydrogen and in catalysts which use energy from the sun to produce hydrogen.  If these technologies can be developed, they would offer cheap, environmentally-friendly means of producing hydrogen.  Again, this is a big if.

So, I wouldn't come to the same conclusion as Zubrin that a hydrogen economy would not work.  However, some major scientific breakthroughs are required before hydrogen would become a commercially-feasible and environmentally-helpful fuel.  So, we should still be putting some research money into hydrogen technologies, we definitely shouldn't be putting all of our eggs in one basket.

On the issue of biofuels, Zubrin is a bit more optimistic than he should be.  Currently, it is not clear whether the production of ethanol from corn is economically or environmentally advantageous since the energy needed to grow, transport, ferment, and distill the corn into ethanol may be more than the energy contained in the ethanol.  Furthermore, growing corn and refining it into ethanol produces other types of pollution, for example, water pollution due to fertilizer use.  On an "ethanol economy" scale, the US would not have enough suitable land to produce enough corn for fuel production while also keeping up with demands for food.

These problems would, however, be overcome by the development of "cellulosic ethanol" technologies, which convert cellulose (IIRC the most common biological material on the planet) into ethanol.  Cellulosic ethanol would allow farmers to grow plants which are less expensive and demanding to grow (e.g. switchgrass) as well as obtain a higher yield of ethanol.  While promising research is going on in this area, the technology is not near the point where it could be implemented yet.  So, like hydrogen, biofuels (ethanol at least) require significant scientific breakthroughs before it can be a viable alternative to gasoline (albeit, cellulosic ethanol is definitely closer to reality than a hydrogen economy).
Title: Re: Hydrogen Economy Fallacy
Post by: enahs on April 04, 2007, 11:12:37 PM
DHMO is also a greenhouse gas!

Yes - but a finite one == unlike carbon dioxide which is not limited

http://www.youtube.com/watch?v=XttV2C6B8pU
If you want to watch a long video. It is quite convincing, and I am willing to believe it, since I have looked at some of the statastical data before, and on a purely statistical basis (which is not always the correct answer) the conclusions are crap, crap crap, even if the theory is 100% correct.

And technically, they are both equally finite, as there are only a certain number of carbon atoms on the earth, and a certain number of hydrogen. So, unless we start making some, or importing some from outside, they are both finite.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on April 04, 2007, 11:31:37 PM
Hydrogen production, as noted by Zubrin, is the more fatal flaw of a hydrogen economy.  However, some promising research is going on in this area, for example, in the biological production of hydrogen and in catalysts which use energy from the sun to produce hydrogen.  If these technologies can be developed, they would offer cheap, environmentally-friendly means of producing hydrogen.  Again, this is a big if.

"This work has shown that it is possible to manipulate molecules and proteins that occur naturally in the human body by changing one small detail of their make-up, such as the type of metal at the heart of a porphyrin molecule, as we did in this study. It's very exciting to prove that we can use these biological structures as a conduit to harness solar energy to produce hydrogen gas from water. In the long term, these synthetic molecules may provide a more environmentally friendly way of producing hydrogen gas, which can be used as a 'green' fuel." - Dr Stephen Curry, a structural biologist from Imperial College London's Division of Cell and Molecular Biology.

Journal Reference
"Photosensitised reduction of water to hydrogen using human serum albumin complexed with zinc protoporphyrin IX", Journal of the American Chemical Society

Teruyuki Komatsu (1, 2), Rong-Min Wang (1, 3), Patricia A Zunszain (4), Stephen Curry (4), Eishun Tsuchida (1).

(1) Advanced Research Institute for Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan
(2) Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi-shi, Saitama 332-0012, Japan
(3) Gansu Key Laboratory of Polymer Materials, Northwest Normal University, Lanzhou 730070, China
(4) Biophysics Section, Division of Cell and Molecular Biology, Faculty of Natural Sciences, Imperial College London, South Kensington Campus, London SW7 2AZ, UK
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on April 04, 2007, 11:36:53 PM
These problems would, however, be overcome by the development of "cellulosic ethanol" technologies, which convert cellulose (IIRC the most common biological material on the planet) into ethanol.  Cellulosic ethanol would allow farmers to grow plants which are less expensive and demanding to grow (e.g. switchgrass) as well as obtain a higher yield of ethanol.  While promising research is going on in this area, the technology is not near the point where it could be implemented yet.  So, like hydrogen, biofuels (ethanol at least) require significant scientific breakthroughs before it can be a viable alternative to gasoline (albeit, cellulosic ethanol is definitely closer to reality than a hydrogen economy).

I believe the secret chemical formula to achieve that is in the hands of scientists at University of Utah. I remembered reading up about a secret chemical substance patented by the University of Utah which can dissolve cellulose to facilitate the synthetic production of ethanol from cellulose.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on April 05, 2007, 12:20:24 AM
I support the methanol economy with a gradual transition from mass usage of internal combustion technology to mass usage of electrochemical oxidation (fuel cell) technology. Existing technology is able to convert Carbon Dioxide to Methanol, which in turns create an economic incentive for CCS.

Let me explain how this would work. Under the Kyoto Protocol, an energy/chemical/etc company would have to pay X £/ton of CO2 emitted to the environment. If a chemical company can convert CO2 to fuel, then the revenue for that chemical company would be (X + Y) £/ton of CO2 where Y is the selling price of the fuel converted from 1 ton of CO2. However, for this work,  the values of X and Y have to be sufficiently high to cover the cost of transporting CO2 and the chemical conversion process. I will not go into the specifics of the technology because I am in the process of securing venture capital and incubation fund to build a demonstration pilot plant.

This technology (chemical conversion) addresses the current issue faced by the CCS sector at the moment. The only economic incentive for CCS at the moment is Enhanced Oil Recovery (EOR). Oil companies are willing to pay the premium to pump the CO2 into depleting oil-fields in order to extend the life of oil fields by 10-15 years in doing so. At the moment, the CO2 for EOR is procured from coal power plants which are situated within 20-30km away from the the oil field. The EOR economy is thus localised by due to geographic restriction of the clients of the CCS Sector - the oil companies. The technology which I am proposing frees the CCS sector from the geographic lock and opens up opportunities for CCS sector to spread all over the country.

In order to harness energy from fuel, we oxidise it via the following reaction: Fuel + O2 -> CO2 + H2O

In reversing the combustion process to convert CO2 to Fuel, Oxygen will be a major by-product which I foresee will have a very good market value. This is because of the increasing strategic importance of oxygen in future energy generation as centralised power plants all over the world will move towards increased efficiency. On top of using the latest coal-gas turbines to generate more power, using oxygen-enriched air will increase the heat obtained from combustion of coal. Oxygen will also play a key role in generating energy from coal fields which are either depleting or too deep. Underground Coal Gasification (UCG) is a process that pumps air or oxygen into deep. Using pure oxygen instead of air increase the calorific value of the coal-gas streaming out of the coal mines by 30-60%. If you let the revenue generated from oxygen sale be Z £/ton of CO2, then the total revenue for such CO2-fuel conversion process would be (X + Y + Z) £/ton of CO2.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Yggdrasil on April 05, 2007, 12:31:23 AM
In reversing the combustion process to convert CO2 to Fuel, Oxygen will be a major by-product which I foresee will have a very good market value.

Where will the energy come from to perform the reverse combusion?

BTW, why did this topic get merged with the other one.  They seem like completely different subjects (aside from the DHMO tangent).
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on April 05, 2007, 12:48:35 AM
BTW, why did this topic get merged with the other one.  They seem like completely different subjects (aside from the DHMO tangent).

I merged them. Isn't the recurring theme for both topics the energy challenge?

Where will the energy come from to perform the reverse combusion?

Renewable and Nuclear. Ellingham Diagram suggests the process requires at least 900C but I managed to find a cheap catalyst which can do the process at 400-600C at less than 10 bar and still have a pretty good yield.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on April 05, 2007, 01:20:19 AM
Just want to add that methanol is a versatile compound. It can be converted into ethene catalytically which is a major petrochemical commodity / feedstock for the manufacture of many chemical products. Converting CO2 to Methanol has a potential of achieving carbon sequestration.
Title: Re: Hydrogen Economy Fallacy
Post by: billnotgatez on April 05, 2007, 04:39:46 AM
I stand corrected ever so slightly.

Carbon dioxide gas is limited by the amount of carbon on the earth and water vapor is limited by approximately 100 % relative humidity. Water vapor can attain less concentration than the carbon dioxide gas even if you imported more hydrogen and carbon from the universe.




DHMO is also a greenhouse gas!

Yes - but a finite one == unlike carbon dioxide which is not limited

Quote
enahs
...
And technically, they are both equally finite, as there are only a certain number of carbon atoms on the earth, and a certain number of hydrogen. So, unless we start making some, or importing some from outside, they are both finite.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: billnotgatez on April 05, 2007, 05:20:13 AM
I must be too cynical. Every time I hear “secret”, I think here comes another conspiracy theory. I must be listening to too much of the “Rollye James Show”.

...
I believe the secret chemical formula to achieve that is in the hands of scientists at University of Utah. I remembered reading up about a secret chemical substance patented by the University of Utah which can dissolve cellulose to facilitate the synthetic production of ethanol from cellulose.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Yggdrasil on April 05, 2007, 11:40:11 AM
Water vapor production is still a pretty valid concern, however.  While it may not contribute to global warming, it could still contribute to climate change.  It's not too much of a stretch to imagine that increased production of water vapor from the energy and transportation sectors would increase the amount of precipitation in some areas.  This could have some pretty profound effects (e.g. increased soil runoff, flooding in areas not meant to handle an increased amount of rain, change of wildlife habitat, etc.).  Of course, it's still not clear whether increased nuclear power/the hydrogen economy would be able to cause such effects, but it's still worth looking into.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Borek on April 05, 2007, 02:17:54 PM
I have a gut feeling that exhaust water - when compared with the amount/speed of natural water evaporation and precipitation and physical properties of the water/vapor/ice system - is of no concern. I suppose rising temperature and increasing evaporation will be much more prominent here.

Assuming annual fuel consuption in US of 170 million gallons, Poland surface of slightly over 310 thousands sq km and 500 mm of annual precipitation in Poland (these are numbers I happened to remember) looks like water from all fuel consumed in all US is equivalent to about 4*10-6 of water falling every year here. Note that Poland is of a size comparable with many US states.

Changes in precipitations year to year are in the few percents range (or more?) - thus even if all water from US transportation system falls here we will be not able to tell the difference. Natural processes plays much more important role, several orders of magnitude higher.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on April 05, 2007, 07:01:23 PM
It took Mankind a few hundred years to emit enough CO2 to cause global warming.

How many more hundred years will we need to achieve global precipitation?
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: constant thinker on April 05, 2007, 09:08:57 PM
How about we just all use straight electricity. Can you say, "Pluggable car."

Ok, I had to propose that one. No one is talking about using straight electricity. I know it has its problems, and coal is the primary source of power (in the U.S.), but with more nuclear power plants and "green" coal plants. It may help to reduce CO2 emissions.

As far as the whole electricity storage problem for cars, I happen to remember hearing about a group at MIT developing a new type of battery using nanotechnology that has the potential to store more electricity per volume than a lithium battery. If I can only find the article again. I'll look for it.

I honestly though, I think the straight electricity thing has a downfall, or any electrical drivetrain for a car, because they are good in stop and go situations, but what about on the highway. Around here, I'm regularly doing 70-80mph on the highway. If I recall correctly it would take quite a bit of electricity to maintain that speed.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Borek on April 06, 2007, 07:23:51 AM
It took Mankind a few hundred years to emit enough CO2 to cause global warming.

How many more hundred years will we need to achieve global precipitation?

I know this argument, but I don't think it applies here. There is not enough oil left to produce enough gas so that exhaust water will become substantial participant in precipitation.

Also note that we are talking about completely different processes (CO2 assimilation and water precipitation). One is biological, second is pure physics. I have no idea about exact numbers but if someone feels like checking - my bet is that increase of the average annual Earth temperature by 0.1 deg C means higher increase in the amount of water in the air (water from natural sources) than we can produce burning all oil we know off. Water from exhaust is negligible in this system.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on April 06, 2007, 09:17:24 AM
How about we just all use straight electricity. Can you say, "Pluggable car."

There are so many proposals on what the future technology is. What is lacking is the bridge to the future.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: billnotgatez on April 06, 2007, 12:43:20 PM
How about we just all use straight electricity. Can you say, "Pluggable car."
...

Where does the electricity come from that you "Plug" into?

For this exercise assume that Fusion Nuclear will still be in the experimental stage for 100 years and you do not have di-lythyum crystals (as in Star Trek).
Title: Re: Hydrogen Economy Fallacy
Post by: enahs on April 06, 2007, 08:55:56 PM
I stand corrected ever so slightly.

Carbon dioxide gas is limited by the amount of carbon on the earth and water vapor is limited by approximately 100 % relative humidity. Water vapor can attain less concentration than the carbon dioxide gas even if you imported more hydrogen and carbon from the universe.



Aww come on. You had me quoted about the finite number of carbon and hydrogen. You where supposed to mention that finite quantity is oxygen, as they share oxygen in common.

Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: billnotgatez on April 06, 2007, 10:25:32 PM
You know I thought about that and then said “Naaw he won’t catch me on that”. I am just tooo slow sometimes.

Quote
Aww come on. You had me quoted about the finite number of carbon and hydrogen. You where supposed to mention that finite quantity is oxygen, as they share oxygen in common.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: billnotgatez on April 07, 2007, 12:50:45 PM
Is anyone going to take up the gauntlet and make suggestions for the plug in source of energy?

I was just listening to a radio program that said that there is not enough crops to make bio-energy in the USA. Well at least not enough ethanol could be made. Would methanol be better?

Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Yggdrasil on April 08, 2007, 04:05:59 PM
I was just listening to a radio program that said that there is not enough crops to make bio-energy in the USA. Well at least not enough ethanol could be made. Would methanol be better?

Using current technologies which make ethanol from corn, the US would not have the capability to fuel more than ~30% of its vehicles with ethanol.  The ability to make ethanol from cellulose could greatly expand our capabilities to produce ethanol but the technology is still in development and the costs associated with creating cellulosic ethanol have not been well established.

Also, I don't know how methanol differs from ethanol as a fuel and in its production.  Does anyone have any information on this?
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: billnotgatez on April 08, 2007, 08:54:33 PM
http://www.chemicalforums.com/index.php?op=Articles;article=26
The above has a discussion of bio-fuels which I am rereading.

http://www.methanol.org/
Of course the above comes from a biased group but may have useful information.

When spouting out opinions one has to do ones research and try to understand if there is any bias.

For instance Ralph Nader would be biased, he may also be correct. Notice the operative word is may.

Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: constant thinker on April 09, 2007, 09:38:17 PM
I think it was Borek or maybe geodome that had calculated how much land it would take to produce enough fuel to satisfy the U.S.'s demand for energy.

Does anyone else remember this because I can't find the topic/post.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: billnotgatez on May 18, 2007, 01:11:45 PM
Fill your car up with aluminum?
http://news.yahoo.com/s/nm/20070518/us_nm/fuel_hydrogen_dc
why did we not know about this before
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on May 18, 2007, 11:07:09 PM
Let's analyse how Aluminium would work out as hydrogen for transport:

Assumptions
Density of Gasoline = 737.22 kg.m-3 = 2.7907 kg/gallon
Efficiency of Internal Combustion Engine (ICE) = 35%
Efficiency of H2 Fuel Cell (FC) = 60%
 
Substance  Energy Density
1. Hydrogen Gas120 MJ/kg
2. Ethanol 23.4 MJ/kg
3. Gasoline 45 MJ/kg
4. Diesel 45 MJ/kg
Vehicle TypePetrol Mileage  ICE Consumption FC Consumption
1. Passenger Car22.4 Miles/Gallon2.769 kJ/Mile1.615 kJ/Mile
2. Vans, Pickups, SUVs 16.2 Miles/Gallon3.828 kJ/Mile2.233 kJ/Mile
3. Trucks 06.7 Miles/Gallon9.259 kJ/Mile5.402 kJ/Mile
4. All Vehicles 17.1 Miles/Gallon3.627 kJ/Mile2.116 kJ/Mile
On a basis of 1000 miles
Vehicle TypeH2 RequiredH2O RequiredAl RequiredGasoline Required
1. Passenger Car0.0135 kg0.1215 kg0.1214 kg124.6 kg
2. Vans, Pickups, SUVs 0.0186 kg0.1674 kg0.1673 kg172.3 kg
3. Trucks 0.0450 kg0.4050 kg0.4047 kg416.5 kg
4. All Vehicles 0.0176 kg0.1584 kg0.1583 kg163.2 kg

There is storage space available for 158g of water and 158g of Aluminium. Their total space storage would be so much less than the space required for 163.2 kg of gasoline (58 gallons).

(https://www.chemicalforums.com/proxy.php?request=http%3A%2F%2Fgeodome.chemicalforums.com%2FAl_Price.png&hash=493c55ab569c020cb847cc8c58e33c3893d47cf1)
Price of Aluminium on London Metal Exchange (http://www.lme.co.uk) (US$/25tons)

Based on the price peak (US$3000 / 25 tons) in the above chart, the price of aluminium for topping up an average vehicle is $0.02. However, if one to take in account of the effect of supply and demand of Aluminium for transport, I would not be surprised that Aluminium price would grow to at least 50-70X its current price. Taking in account of logistics, tax and profit, one might expect the the price increment of $100-200/kg. A more realistic price for Aluminium at "petrol" kioks would be $2-4 per 1000 miles, compared to $1.50/gallon for petrol.
 
But there are definitely challenges in implementing this technology.
1. The availability of Gallium to store Aluminium in the form of a liquid alloy
2. Will the liquid alloy freeze in winter?
3. Controlling hydrogen production rate at the micro-gram level in a car
4. Separating Al2O3 from the Gallium alloy
5. Can Aluminium be regenerated via electrolysis in liquid Gallium?


Reference:
1. Energy Density Data: http://hypertextbook.com/facts/2003/
2. Transport Consumption (USA, 2004): http://www.eia.doe.gov/emeu/aer/txt/ptb0208.html
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: constant thinker on May 19, 2007, 09:14:20 PM
Nice tables geodome.

This is something to keep an eye out for. It'll be interesting to see if this technology winds up working on a commercial scale.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Sam (NG) on May 21, 2007, 06:45:01 PM
The aforementioned cellulose-->ethanol catalyst: http://www.rsc.org/chemistryworld/News/2006/July/13070601.asp

Requires Hydrogen gas, hmm, wonder if it would be preferred just to use hydrogen as a fuel.

I have the possibility of joining a research group on NiFe hydrogenase scalability next academic year. (Water to hydrogen and oxygen).  Worth joining?
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Woofuls on July 08, 2007, 12:36:35 AM
Note: I did not stick numbers anywhere, I'm sure that the CO2 is worse than water vapor as a green house gas.

It depends what you mean by worse... Water vapor absorbs thermal radiation, from the sun, BETTER than carbon dioxide.

Anyway, about energy in general...

What I dislike seeing is how people push other individuals toward ONE solution: "IT'S NUCLEAR ALL THE WAY BABY." "Screw Chernobyl, how about some corn, every one likes corn because it sounds a lot like porn," and etc.

Finding just one solution doesn't happen all that much in math. In some systems, there are infinite ways to express the solution. So, why can't our energy solution be made up by a variety of "equations"? It doesn't all need be just ethanol or methanol or geothermal or fission... that is, until fusion matures. ;-)

I think we should keep plucking away (RESEARCH!!) on many different projects and try them out in the real world. Every system will have its cons and pros. It seems to me, that by utilizing many different technologies you will get a smaller amount of the cons (i.e. at the least the cons will be spread out and seem far less grisly and manageable rather than having them clumped together in a massive pile) while getting all the pros. It just seems logical until research finds better stuff.

My $0.23 ;)
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on July 10, 2007, 06:05:51 PM
It is easy to have a variety of fuel for electricity generation but it wouldn't be the case for transport, unless we switch to electric vehicles.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: enahs on July 11, 2007, 09:43:04 AM
Geodome, now do another fancy chart (which is not easy on the forum!) about the energy and pollution produced mining and refining Aluminum as compared to fossil fuel or obtaining hydrogen from water.


Producing aluminum is one of the most energetically expensive mass industrial processes in use today. And since most of our energy on "the grid" comes from burning fossil fuels, is it really any better?
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Donaldson Tan on July 11, 2007, 06:19:02 PM
Enahs: you mean do a Life Cycle Assessment of Aluminium Production..That will take me a while to gather all the required data.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming..
Post by: Woofuls on July 15, 2007, 11:26:22 PM
It is easy to have a variety of fuel for electricity generation but it wouldn't be the case for transport, unless we switch to electric vehicles.

Having more than one type of fuel is possible for transport. For example, diesel and gasoline are served at every fuel station I've ever been. Being "easy" is debatable, but if there is a great enough demand then some company will try to supply it.

I do agree that electricity is the future! :)
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming...
Post by: Donaldson Tan on July 17, 2007, 03:51:17 PM
However, this issue has to be reconsidered from another point of view.

Are you familiar with the concept of Vendor Lock-in (http://en.wikipedia.org/wiki/Vendor_lock-in)?

Being "easy" is debatable, but if there is a great enough demand then some company will try to supply it.

It is easy to choose the fuel type for electricity generation because it is an investment for utility companies and they will get a good return on investment. In view of declining supply of fossil fuel, it is strategically better to adopt IGCC which has thermal efficiency of generating electricity at 40-45%. IGCC can run a variety of biomass fuel, on top of traditional fossil fuels.

There is no positive cash flow generated from purchasing a vehicle for personal transport. Personal transport accounts for an overwhelming majority of vehicles in the transport sector. Although a personal vehicle generates intangeble benefits such as convinience, it is still a liability as it has a regular operations and maintenance (O&M) cost on top of the one-off purchase price. O&M cost includes road tax, carbon tax (if there would be one), fuel price, etc.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming...
Post by: sluiceman on April 27, 2008, 10:05:36 PM
Yes, Hydrogen as a fuel.
I believe this line of thought should be revived.
Last summer in the Minneapolis area I produced hydrogen on-board in my old Ford Van. I used Sodium Hydroxide (could also have used Potassium Hydroxide) and scrap aluminum to get an extra ~100 extra miles per tank of gas. I used a single 500mL Pyrex flask, rubber stoppers with appropriate holes, sections of glass tubing, some refrigerator ice maker tubing, a second Pyrex flask as a water scrubber unit and a one way valve designed for aquarium use to keep the engine idle vacuum,which builds up in the reactor unit, from siphoning water from the scrubber into the reactor unit. The Hydrogen I produced was fed into a vacuum port on the intake manifold. The flow chart goes like this; From the reactor unit through the one way valve to the scrubber unit. From the scrubber unit to the vacuum port on the intake manifold.
It was all very simple. A couple tblsp of caustic and a couple ounces of Aluminum would "boil" Hydrogen for nearly an hour and a half. When the pressure was sufficient it would overcome the resistance of the valve. This happens mostly on level or downhill runs. With two or more reactors the pressure will be positive most of the time.
Since this is an exothermic reaction I placed the works on a hot pad in a Rubbermaid enclosure. I didn't even blow myself up. I really believe the explosive nature of Hydrogen is greatly over rated. I vented off a lot of Hydrogen doing this. It immediately dispersed and floats away, unlike gasoline fumes.
Yes, aluminum is expensive in terms of cost and energy consumption. But, it is nevertheless produced and it is available as scrap. Also, This is somewhat messy and inconvenient for short trips, and the thing freezes in the winter. This could be overcome by doing this in my garage and using a compressor for storage.
If you're wondering, I got this idea from a book that was published in 1919 by P. Litherland Teed, The Chemistry and Manufacture of Hydrogen. During WW2 Hydrogen was produced in vast quantities for lighter-than-air craft. They didn't use petroleum fuel to produce electricity to evolve Hydrogen by electrolysis of water (this is a net loss, and is why the current proposal for a Hydrogen Economy is a farce). Instead, Teed outlined perhaps a dozen methods of producing Hydrogen. The most viable and economically feasible method uses Sodium Hydroxide and ferosilica (Yes, sand) of sufficiently high silica content. The "Silicol Process" begins on page 45 of the book and is expressed as:
2Si + 2NaOH + 3 H2O = Na2Si2O5 + 2H2
Government and the energy industries surely know this. We could be producing Hydrogen for practically nothing. Makes me wonder.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming...
Post by: Borek on April 28, 2008, 03:02:11 AM
They didn't use petroleum fuel to produce electricity to evolve Hydrogen by electrolysis of water (this is a net loss, and is why the current proposal for a Hydrogen Economy is a farce). Instead, Teed outlined perhaps a dozen methods of producing Hydrogen. The most viable and economically feasible method uses Sodium Hydroxide and ferosilica (Yes, sand) of sufficiently high silica content. The "Silicol Process" begins on page 45 of the book and is expressed as:
2Si + 2NaOH + 3 H2O = Na2Si2O5 + 2H2
Government and the energy industries surely know this. We could be producing Hydrogen for practically nothing. Makes me wonder.

You are aware of the fact that NaOH is industrially produced by electrolytical method, so using NaOH to avoid electrolysis is in fact biting your own tail? Back then NaOH was produced by other methods (Leblanc/Solvay to get Na2CO3, then roasting of carbonate and reacting Na2O with water), but electrolytical methods proved to be cheaper.

Then, ferrosilicon is not a sand. It is an alloy made by reducing sand with coke in the presence of iron. It requires waste amounts of energy to be prepared.

I wouldn't call it "practically nothing".

http://en.wikipedia.org/wiki/Sodium_hydroxide
http://en.wikipedia.org/wiki/Ferrosilicon
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming...
Post by: sluiceman on April 28, 2008, 08:19:24 AM
Good point.
I mentioned that KOH can also be used, which is not made by electrolytic methods.
also, Tailings sands, waste sand from the processing of the Athabasca Oil Sands, average 95 to 98 percent silica (SiO2) in the raw bulk samples. According to Teed, sands averaging 84-92% can be used in this process. Perhaps other sands can be obtained of similitude. Would the O2 create additional problems?
I'm trying to find a way this can work.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming...
Post by: Borek on April 28, 2008, 08:50:10 AM
I mentioned that KOH can also be used, which is not made by electrolytic methods.

As far as I know it is made electrolytically as well.

Quote
also, Tailings sands, waste sand from the processing of the Athabasca Oil Sands, average 95 to 98 percent silica (SiO2) in the raw bulk samples. According to Teed, sands averaging 84-92% can be used in this process. Perhaps other sands can be obtained of similitude. Would the O2 create additional problems?

You are mistaking two completely different things - silicon (Si) with silica (SiO2). The difference is similar to that between gasoline and exhaust gases.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming...
Post by: sluiceman on April 30, 2008, 09:37:18 AM
Well, That's OK.

I buy NaOH by the drum for a reasonable price, and I have more scrap aluminum than I can use. I'll make my own Hydrogen again this summer.
Title: Re: Hydrogen Economy Fallancy, Nuclear Power Plants, Global Warming...
Post by: tasmodevil44 on July 08, 2008, 05:53:15 PM
Scientific expert Klaus Lackner and many others believe that direct carbon dioxide capture from the atmosphere to make methanol and other hydrocarbons is indeed possible.Furthermore,methanol is the starter molecule for synthesizing all these other much larger hydrocarbons.It may indeed turn-out to be better than the hydrogen economy due to bulkiness of space and storage costs.What is methanol itself but a convenient way of molecular hydrogen storage that a methanol fuel cell can use?

      Shhh...be very quiet...some people might think you're talking about a million litres of perpetual motion alcohol originally made from just one molecule ! ! ! LOL ! ! ! Heh,heh,heh.. :D