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Topic: Calculating the slope of a calibration curve of a voltaic cell...?  (Read 11201 times)

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Offline o1ocups

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A voltaic cell designed to measure [Cu2+] is constructed of a standard hydrogen electrode and a copper metal electrode in the Cu2+ solution of interest.

If you wanted to construct a calibration curve for how the cell potential varies with the concentration of copper(II), what would you plot in order to obtain a straight line? Ans: log[Cu2+] versus EĀ°cell

But what would be the slope of the line?

I changed the Nernst equation around and got 34 but I think it's wrong  :-\
« Last Edit: April 05, 2009, 09:44:14 PM by o1ocups »

Offline o1ocups

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Re: Calculating the slope of a calibration curve of a voltaic cell...?
« Reply #1 on: April 05, 2009, 10:34:25 PM »
 Someone give me a hint please?

Offline Borek

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Re: Calculating the slope of a calibration curve of a voltaic cell...?
« Reply #2 on: April 06, 2009, 02:56:32 AM »
34 of what?

Show how you got it, hard to help not knowing what and how you did.
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Offline o1ocups

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Re: Calculating the slope of a calibration curve of a voltaic cell...?
« Reply #3 on: April 06, 2009, 01:22:35 PM »
Forget what I did, it is completely wrong. The correct answer is 0.0296 V but I have no idea how they got that answer. I thought it might have something to do with changing the Nernst equation around to fit the y=mx+b form but if not I really have no idea where to start.

Offline Borek

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Re: Calculating the slope of a calibration curve of a voltaic cell...?
« Reply #4 on: April 06, 2009, 05:00:11 PM »
This is pretty simple. Write Nernst equation for your cell.
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