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Topic: Chemical kinetics  (Read 2017 times)

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Offline NitricAcid

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Chemical kinetics
« on: August 02, 2013, 05:32:37 AM »
I need help on this problem, anyone know how to solve it? thanks

In the thermal decomposition of compound A on vidreo: 2A (g) -> 2B (s) +3 C (l), it was found that the total system pressure varied with time at 350 ° C, according to sample in the table.

t (h)           0      16      37.66     45.6     91.2     136.8
 p (mmHg)   42.1  43.8   46.06      46.99    52.98    59.14

Calculate: order of reaction with respect to A, and the rate constant

The question I have is this: if you only count the gas pressure,

  
Why pressure increases when decreasing the concentration of the gas?


Offline Babcock_Hall

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Re: Chemical kinetics
« Reply #1 on: August 02, 2013, 10:08:53 AM »
It is odd that pressure is rising, not falling.  It is also odd that the data do not extend to equilibrium, from the look of things.

Offline curiouscat

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Re: Chemical kinetics
« Reply #2 on: August 02, 2013, 10:50:43 AM »
It is odd that pressure is rising, not falling.  It is also odd that the data do not extend to equilibrium, from the look of things.

Only thought I had was, would the vapor pressure of C be at all relevant here? What if C was a high vapor pressure liquid?

Not sure though; I'm still confused.

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