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Topic: Question on Chemical Kinetics  (Read 2119 times)

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Offline Ready2Learn

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Question on Chemical Kinetics
« on: February 14, 2012, 03:30:32 PM »
Hi all! I had a question....

Question 1: A reaction with activation energy of 123kJ/mole has  rate constant of 0.200s^-1 at 38 degrees Celsius. At what temperature will its rate constant be double that at 38 degrees Celsuis

Formula used: ln(k2/k1)=-(Ea/R)[(1/T2)-(1/T2)]

Attempt:  
T1=(38+273K)=311K
T2=?
Ea=123,000J/mole (needs to be converted from kJ->J)
R=8.314 J/mol*k
k1=.200s^-1
k2=(.200s^-1)(2)=.4s^-1

I was wondering how to change the formula for this particular question

I know you need to first get (1/T2) and (1/T1) on one side and -(Ea/R) and ln(k2/k1) on the other....would the ln(k2/k1) be divided by (Ea/R) or multiplied?

Thank you



Offline UG

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Re: Question on Chemical Kinetics
« Reply #1 on: February 14, 2012, 04:45:39 PM »
Say I let a =(1/T2)-(1/T1)
b = -(Ea/R)
and c = ln(k1/k2)
So that the equation becomes c = ba, how would you isolate 'a' on one side? :)

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