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Topic: Conformation of cyclohexane  (Read 5025 times)

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Offline Agent-X

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Conformation of cyclohexane
« on: June 29, 2009, 02:54:52 AM »
I'm reading that the chair conformation of cyclohexane (staggered) has C-C-C bond angles of 111o. What does that mean? I don't understand that. I'm looking at the ball-and-stick model, but I'm trying to figure out what it's exactly referring to in the model.

Is it the vertex angle I drew out that is being referred to?
« Last Edit: June 29, 2009, 03:22:44 AM by Agent-X »
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Offline lancenti

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Re: Conformation of cyclohexane
« Reply #1 on: June 29, 2009, 11:09:16 PM »
111.jpg should be right.

Offline AWK

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Re: Conformation of cyclohexane
« Reply #2 on: June 30, 2009, 03:31:31 AM »
Quote
I'm trying to figure out what it's exactly referring to in the model.
This concerns all C-C-C angles of the six-membered ring.
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Offline 18uos

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Re: Conformation of cyclohexane
« Reply #3 on: July 01, 2009, 01:02:07 PM »
your figure seems to be not understandable
 :'(
I'm reading that the chair conformation of cyclohexane (staggered) has C-C-C bond angles of 111o. What does that mean? I don't understand that. I'm looking at the ball-and-stick model, but I'm trying to figure out what it's exactly referring to in the model.

Is it the vertex angle I drew out that is being referred to?

Offline Agent-X

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Re: Conformation of cyclohexane
« Reply #4 on: July 01, 2009, 08:31:04 PM »
your figure seems to be not understandable
 :'(
Is it the vertex angle I drew out that is being referred to?

That's ok, because I'm not sure how to ask.

I know that the hexagon bends at its carbons. What I'm trying to figure out if the interior angles stay at 111o degrees all the time. When cyclohexane changes its conformations does it keeps its interior angles at 111 degrees?

What about cyclohexane is 111 degrees? I see the 3D model, but it's not blatently obvious what is exactly 111o in the diagram.
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Offline lancenti

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Re: Conformation of cyclohexane
« Reply #5 on: July 03, 2009, 04:11:06 AM »
You can look at the Boat Conformation just like a Chair Conformation, just that instead of one carbon above and one below, both are above/below the plane of the four other carbon atoms. I suspect that it is still 111 degrees, or close to it.

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