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Topic: Combustion of Iron  (Read 16309 times)

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Offline schmitgreg

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Combustion of Iron
« on: October 19, 2007, 02:54:49 PM »
I would like to verify my belief about combustion of Fe (Iron).

This is the basic equasion I get:
Fe + O2 => Fe2O3

I have two different possible (I Think) equasions that are balenced:
4Fe + 3O2 => 2Fe2O3
and also:
2Fe + O2 => 2FeO

I want to make sure that I am producing Fe2O3 and not FeO.

My method is burning steel wool (Fe mostly) in order to get the Fe2O3, so it there a way to make sure that I only get the molecule I want, or is it left up to chance?

Also, if it is chance, about how much FeO will I get in relation to Fe2O3?

Thanks guys!

Offline enahs

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Re: Combustion of Iron
« Reply #1 on: October 19, 2007, 04:04:17 PM »
FeO is unstable and is easily turned into Fe2O3 in the presence of oxygen.


No worries about producing appreciable amounts of FeO with your method.


Offline schmitgreg

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Re: Combustion of Iron
« Reply #2 on: October 19, 2007, 04:58:53 PM »
I'm not that far into chemistry, but I'm interested in this:

What makes FeO unstable? If iron likes to lose 2, 3, or 6 electrons and Oxygen likes to take 1 or 2 electrons then what about FeO is unstable?

I'm sorry if this seems elementary but i have just started chemistry and I'm interested.

Also, the compound made by combusting Fe is Fe2O3. However I have read from wikipedia (which could be just plain wrong) that FeO is suceptible to becoming Iron(III) Oxide (Fe2O3) which I thought was rust. Wikipedia says that it is not rust, and this confuses me. Fe2O3 is the exact same thing as rust right??

Here is the link:
http://en.wikipedia.org/wiki/Iron(II)_oxide

Offline enahs

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Re: Combustion of Iron
« Reply #3 on: October 20, 2007, 10:38:59 AM »
The wiki article says not to confuse Iron(II) Oxide with rust, which is considered Iron(III) Oxide (Fe2O3). You just misread wiki.


When I say unstable, I was probably confusing and wrong for saying it like that.  In this specific reaction it is either slightly less thermodynamically stable, and thus Fe2O3 forms more, or just as likely it is not as kinetically favorable  (forms slower the Fe2O3).


And FeO is easily turned into Fe2O3 in the presence of OH-, I do not know what I was thinking yesterday.


Offline schmitgreg

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Re: Combustion of Iron
« Reply #4 on: October 20, 2007, 06:29:43 PM »
Awesome, thanks for the info.

Yeah, you are right, I thought it was saying Iron (III) Oxide.

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