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Topic: Calculating ion concentrations  (Read 5574 times)

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Offline govibe

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Calculating ion concentrations
« on: September 29, 2007, 11:24:16 PM »
These "ion concentrations after equation" problems are a challenge for me.

"Calculate the sodium ion concentration when 60.0 mL of 8.5 M sodium carbonate is added to 30.0 mL of 1.0 M sodium bicarbonate."
OK, I first converted both the sodium carbonate and sodium bicarbonate quantities into moles... Since there are two sodium ions per sodium carbonate ion, I multipled that value by two... I then added that value with the moles of sodium ion in sodium bicarbonate, which comes out to 1.05 moles. I then divide that by .09L to get 1M, which isn't the right answer. Can someone point out what I should have done?

Offline Borek

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Re: Calculating ion concentrations
« Reply #1 on: September 30, 2007, 03:37:43 AM »
which comes out to 1.05 moles

Check your math. From your description you are approaching problem correctly, but 1.05 is about twice too much.
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Offline govibe

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Re: Calculating ion concentrations
« Reply #2 on: September 30, 2007, 10:21:39 AM »
this is what I did

(.06L)(8.5M)2=1.02mol
(.03L)(1.0M)=.03mp;

1.02 +.03=1.05mol

1.05mol/.09L = 11.6666666M

What am I doing wrong?

Offline Borek

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Re: Calculating ion concentrations
« Reply #3 on: September 30, 2007, 10:47:57 AM »
Sorry, my mistake. Your result is OK (although it is not 1M you gave earlier).

Are you sure it is 8.5M? Looks like it is quite above carbonate solubility (about 3.75 M for saturated solution at 25 deg C)
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Offline govibe

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Re: Calculating ion concentrations
« Reply #4 on: September 30, 2007, 11:32:01 AM »
Yes, it is 8.5M...

Apparently, the answer to this problem is 12M...

Offline enahs

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Re: Calculating ion concentrations
« Reply #5 on: September 30, 2007, 12:19:56 PM »
In your original question as you typed them your concentrations only had 2 sig figs, so your answer must be limited to 2 as well.

11 (2/3) gets rounded up to 12.


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