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Topic: Acids and Bases in Hydrolysis ?  (Read 1853 times)

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Offline shalikadm

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Acids and Bases in Hydrolysis ?
« on: June 15, 2012, 09:01:52 AM »
What I understand about hydrolysis is split of H2O into H+ and OH-.
I don't know the reason to use NaOH or H2SO4 in hydrolysis..
For an example let's take hydrolysis of Acid anhydride.
We can hydrolyze it with H2O
(RCO)2O+H2O :rarrow: 2RCOOH]
We can also use aqueous NaOH in hydrolysis..

What I understand from the above equation is that H2O is split and reacts to give an acid(RCOOH).and then NaOH,the base reacts with it to give a salt.So here H2O only contribute in hydrolysis.Am I correct ?

Lets take this hydrolysis.

Does this happen in this way?

If it is so.I think that here only H2O contributes to the hydrolysis..Am I correct ?
The above hydrolysis of amide can be also done using sulfuric acid.


Let's take this one..here it uses H2SO4 for hydrolysis.


From all of above I think that acids and bases are used only as catalysts..Am I correct ?

Offline Schrödinger

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Re: Acids and Bases in Hydrolysis ?
« Reply #1 on: June 15, 2012, 12:16:29 PM »
Yes. They are mere catalysts. Water is not ionized very easily, or it is not a good enough nucleophile on its own, or something like that, always.
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