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Topic: Balancing RedOx Reactions in Acidic or Basic Aqueous Solution  (Read 5107 times)

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Offline imperius

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Compose the balanced reaction equation for the following reaction occuring in acidic aqueous medium.
Reduce all coefficients to the lowest possible integral values.
Include H2O(l) and H+(aq) appropriately to complete the equation.

As2S3(s) + NO3−(aq) → H3AsO4(aq) + NO(g) + S8(s)

Problems:
1. What are the individual oxidation states for As2S3?
2. How do you find the half reactions?

Offline Borek

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Re: Balancing RedOx Reactions in Acidic or Basic Aqueous Solution
« Reply #1 on: March 01, 2008, 03:21:11 PM »
S in sulfides - always -2.

I would go for half reactions method (ignoring oxidation numbers)

http://www.chembuddy.com/?left=balancing-stoichiometry&right=half-reactions-method

With these half reactions:

As2S3(s) → H3AsO4(aq) + S8(s)

NO3(aq) → NO(g)
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