Experimentally, to determine the boiling point of a compound, you either need to isolate the compound in its pure liquid form and warm it up until it boils, or isolate the compound in its pure gaseous form and cool it down until it condenses. This compound is not stable enough to isolate in either a pure liquid or pure gaseous form. It is generated in situ in a solvent, and reacted without isolating it. When you try to isolate it, it decomposes.