May 30, 2024, 04:08:50 PM
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Analytical Chemistry Forum / Re: Acid chloride TLC
« Last post by Tom_Boomer on Today at 12:20:04 PM »
Thank you for your response wildfyr! In regards to:
the product on the baseline is the starting material, the one that runs is the ester.
I assumed the same at first, however, I started to wonder as to why at the sample at T0 there would be no dot in that case, even though the starting product dissolves in the DMF. Hence, me wondering what it could be.
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Basic physics. Work/energy and force are different fundamental physical concepts. Knowing the force at _some_ point of the bond breaking process is not enough to say how much work needs to be done to achieve separation.
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Oh, you've excelled yourself this time!
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High School Chemistry Forum / Re: CH4 combustion exercise
« Last post by mjc123 on Yesterday at 06:00:47 PM »
Please read the forum rules; you have to show an attempt of your own before receiving help.

In any case, I don't know what a lambda factor is, I don't know what the selected equilibrium reaction is, and I don't have the basic thermodynamic information to hand. Is this information that is provided in the question paper but you are withholding from us? How do you expect anyone to solve this problem?
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Why isn't Bond Enthalpy/Bond disassociation energy measured as a force?

I understand every bond chemically has a length and energy to break, and energy is Newton*meters, but force is Newtons.
Is the Bond enthalpy/Bond disassociation energy equivalent to the force needed to break the bond * the bond length?

Why don't we say, to break the bond from O to H we need to put magnets on left of the O and right of the H and apply some pulling force of XYZ?
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High School Chemistry Forum / CH4 combustion exercise
« Last post by Thoma64 on Yesterday at 04:26:12 PM »
Hello everyone,
I am posting this message because I have an exercise to do and I am completely lost. Could you help me on how to do it? :

Exercise:
Consider the combustion of methane with regular air. Inlet temperatures of methane and air are 300 K and 400 K, respectively. The mass flow rate of air is 0.1 kg/s, and the lambda factor is 0.9.
This is a case of a rich mixture (λ<1). In this case, the species in the products will contain CO2, H2O, CO, H2, and N2, among other species. Mass (or atoms) conservation is not enough to close the problem.

1) Considering only the five species in the products mentioned above, evaluate the Kp of the selected equilibrium reaction based on the basic thermodynamic information (enthalpies of formation, molar heats and reference entropy of the species involved).

2) Evaluate the concentration of the five species considering Tcc=1400 K

3) Evaluate the combustion temperature and the concentration of the five species (global itetaive process)

Thank you for your help. This exercise is very important to me.
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sounds like gypsum is the likely culprit.  thank you!
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High School Chemistry Forum / Re: Mineral reactions re: custom sparkling water
« Last post by Hunter2 on Yesterday at 01:30:09 PM »
Any acidic compound react with carbonates to CO2, what will blow up your bags.

Check your compounds, if they are acidic.  Normal salts are neutral. But minerals maybe not.
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What are they?
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Howdy, fellers and ladies!

I am at a loss on the explosive reaction I have been creating and am seeking prof help.

I have been creating sparkling water for the fam for many years and have, in the last 2 years, starting to add minerals back in for flavor and health.  I use reverse osmosis as my starting point and run a custom kegerator set up.

Anyway, my question is regarding the minerals I use appear to 'explode' when mixed together and vacuum packed for later use.

I source high quality lab / food grade USA sourced (when possible).  Here is my list:

Real Salt (Redmond Life)
Potassium Bicarbonate
Epsom salt (aka magnesium sulfate)
Gypsum (aka calcium sulfate)
magnesium carbonate
Calcium Carbonate
Baking Soda (Sodium bicarbonate)
Ascorbic Acid

After the first large batch of this (enough for 20 kegs bc I dont want to mix every single keg we do) I noticed the vacuum packs I did of dry powder expanding big time.

I used what I could and removed the Vitamin C on the next batch  as it clearly had a reaction.  Then I removed the baking soda on the next batch.  I add these two in manually each time to each keg.

Still with those two removed, I made a batch last night, an explosion of powder was what I found.

I would think this is probably some basic high school chemistry that I am just not walking around with.... please let me know/explain what is happening here.


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