May 15, 2024, 12:28:54 AM
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Searleā€™s bar experiment measures thermal conductivity by comparing temperature differences near the heat source and at the ends. However, since the temperatures at the unheated end/heated end often equalize at the beginning/end, the experiment may seem to take an indefinite time to yield results because you can't divide by zero, and I know for a fact that fraction can't be zero so often.



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Organic Chemistry Forum / Re: Bromination
« Last post by Hunter2 on Yesterday at 07:27:57 AM »
Benzoic acid to Di- Nitro Benzoic acid, reduce to Diaminobenzoic acid(ester), then Diazoting and Sandmeyer to Bromo Compound.
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Organic Chemistry Forum / Bromination
« Last post by mujic on Yesterday at 07:12:28 AM »
I want to synthesize methyl 3,5-dibromobenzoate (3,5-dibromobenzoic acid methyl ester).

This can be synthesized from the corresponding benzoic acid, ester, or aldehyde, which are all meta- directing. However, they strongly deactivate the benzene ring and make bromination difficult. Even if the first bromination is achievable, i cannot find any papers on how to do the second one.

I don't have access to an already bromo- substituted benzene compound.

Is there an easier synthetic route? I am struggling in finding any papers for reference.

I am very new to Organic Chemistry and although it seems like an easy target I still find it extremely difficult.
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first of all, since I am not changing concentration, how do I find rate of reaction?

You can't. All you can do is to qualitatively state "this is faster, this is slower". For some applications this is perfectly enough though.

Quote
Also, I am having a hard time understanding what is happening.
CuSO4 was fastest (average of about 10.83 sec for the cross to appear)despite it being +2., and the other two (+1 and +3) were about the same to each other (around 56seconds). I don't understand the pattern, and what is affecting this.
can someone explain why CuSO4 was a better catalyst and why the other two didn't show much difference to each other? I have no clue what is going on and how exactly the catalysts impacted the reation...

You can't base the conclusion on a single run using just three metals. Way too many different factors.

Plus, using Fe(III) compound as a catalyst in the presence of the reacting Fe(III) compound sounds like a nonsense idea - you alrerady have an excess of the cation in the solution, no way to say if addition of a bit more produces catalytic effect.
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I am investigating how different transition metal catalysts (with different charges) affect the rate of reaction between Sodium thiosulfate and Iron(III) Nitrate. My catalysts were Ag(I)NO3, Cu(II)SO4, and Fe(III)Cl3. I observed the reaction from above and recorded the time it took for the cross at the bottom of the reaction became visible.

first of all, since I am not changing concentration, how do I find rate of reaction?

Also, I am having a hard time understanding what is happening.
CuSO4 was fastest (average of about 10.83 sec for the cross to appear)despite it being +2., and the other two (+1 and +3) were about the same to each other (around 56seconds). I don't understand the pattern, and what is affecting this.
can someone explain why CuSO4 was a better catalyst and why the other two didn't show much difference to each other? I have no clue what is going on and how exactly the catalysts impacted the reation...

Please help me. Thank you in advance.
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Analytical Chemistry Forum / Re: Calculation of %Absorbance
« Last post by serotonin on May 13, 2024, 04:50:43 PM »
thanks very much!
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Organic Chemistry Forum / Re: Essential Oil(s) in Rosemary
« Last post by Borek on May 13, 2024, 02:17:51 PM »
I gave chiralic a molesnack, nice help

Yes, nice answer to an 18 years old post , dug out by a newcomer necroposter, probably using ChatGPT to generate reasonably looking answer ;)
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Analytical Chemistry Forum / Re: Spontaneous Process?
« Last post by Babcock_Hall on May 13, 2024, 12:55:10 PM »
Under the assumption that the membrane potential is zero, moving potassium ions from outside to inside is non spontaneous.
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Organic Chemistry Forum / Re: Essential Oil(s) in Rosemary
« Last post by rolnor on May 13, 2024, 12:37:12 PM »
 I gave chiralic a molesnack, nice help
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Analytical Chemistry Forum / Re: Calculation of %Absorbance
« Last post by Corribus on May 13, 2024, 09:40:45 AM »
If the percent transmitted is X, then the percent absorbed is 100-X (with certain assumptions).
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