Chemical Forums
Chemistry Forums for Students => Undergraduate General Chemistry Forum => Topic started by: tomgreenschic on November 05, 2008, 06:33:53 PM
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For some reason I just can't balance this one. Thanks :D
_Na2CO3+_Na2S+_SO2-->_Na2S2O3+_CO2
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I played around with it and got frustrated, so I googled an online balancer (I know Borek has a program also), and it is balanceable. If you decide to throw in the towel, you can go here:
http://www.webqc.org/balance.php
And enter:
Na2CO3 + Na2S + SO2 = Na2S2O3 + CO2
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Tricky, but doable. I have converted it ifrst to
Na2O + Na2S + SO2 -> Na2S2O3
(CO2 can be always added on both sides) but it didn't help much.
Then I realized it is almost balanced - the only problem is, there is too much sodium on the left. Playing with Na2O and SO2 I will always need more sulfur (two atoms per thiosulfate). So I decided to try 2Na2S and the rest was a breeze. But that's more luck than a systematic approach.
Systematic approach will be to use algebraic method (http://www.chembuddy.com/?left=balancing-stoichiometry&right=algebraic-method).
And yes, my EBAS balances this equation in no time.
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Na2CO3 + Na2S + SO2 = Na2S2O3 + Na2S2O3 + CO2
Use oxidation number method - this will give you 2Na2S + 4SO2 on the left and 3Na2S2O3 on the right side. Adjusting number od Na2CO3 is straighforward.